Molecular packing of surface active ionic liquids in a deep eutectic solvent: a small angle X-ray scattering (SAXS) study
Li, QT (Li, Qintang)[ 1 ]; Tong, K (Tong, Kun)[ 2 ]; Qiu, J (Qiu, Juan)[ 3 ]; Yan, MH (Yan, Minhao)[ 1 ]; Tian, Q (Tian, Qiang)[ 1 ]; Chen, X (Chen, Xiao)[ 3 ]; Yue, X (Yue, Xiu)[ 4 ]
2019
Source PublicationSOFT MATTER
ISSN1744-683X
Volume15Issue:25Pages:5060-5066
Abstract

During the past decade, deep eutectic solvents (DESs) have shown promising application in the self-assembly of surfactants. Various aggregates such as micelles, vesicles, lyotropic liquid crystals, microemulsions and gels have been reported. In this research, the phase behaviours of imidazolium surface active ionic liquids (SAILs) C(n)mimBr (n = 12, 14, 16) were investigated in ChG. With the help of small angle X-ray scattering (SAXS), the types and structure parameters of aggregates were determined. The molecular packing of SAILs was influenced by the solvophobic chain length, surfactant concentration, temperature and solvent, accounting for their different aggregation behaviours. This study would give a good description of the molecular packing of surfactants in DESs.

DOI10.1039/c9sm00760a
Indexed BySCI
WOS IDWOS:000473053500005
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/6030
Collection中国科学院特殊环境功能材料与器件重点试验室
Affiliation1.Southwest Univ Sci & Technol, State Key Lab Environm Friendly Energy Mat, Mianyang 621000, Sichuan, Peoples R China
2.Beijing Inst Aerosp Testing Technol, Beijing Key Lab Res & Applicat Aerosp Green Prope, Beijing 100074, Peoples R China
3.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China
4.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Li, QT ,Tong, K ,Qiu, J ,et al. Molecular packing of surface active ionic liquids in a deep eutectic solvent: a small angle X-ray scattering (SAXS) study[J]. SOFT MATTER,2019,15(25):5060-5066.
APA Li, QT .,Tong, K .,Qiu, J .,Yan, MH .,Tian, Q .,...&Yue, X .(2019).Molecular packing of surface active ionic liquids in a deep eutectic solvent: a small angle X-ray scattering (SAXS) study.SOFT MATTER,15(25),5060-5066.
MLA Li, QT ,et al."Molecular packing of surface active ionic liquids in a deep eutectic solvent: a small angle X-ray scattering (SAXS) study".SOFT MATTER 15.25(2019):5060-5066.
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