(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties
Abudoureheman, M (Abudoureheman, Maierhaba)[ 1,2 ]; Pan, XB (Pan, Xiaobo)[ 1 ]; Han, SJ (Han, Shujuan)[ 1 ]; Rouzhahong, Y (Rouzhahong, Yilimiranmu)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Wu, HP (Wu, Hongping)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
2018
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume57Issue:12Pages:7372-7379
Abstract

By the application of cation substitution, five new members of cyclophosphates, RbCdP3O9, CsPbP3O9, CsSrP3O9, RbMgP3O9, and RbCaP3O9, were obtained by a high-temperature melt method and structurally analyzed. The five compounds have identical stoichiometries, and all of them feature a three-dimensional network, which consists of (MO6)-O-II (M-II = Cd, Mg, Ca, Pb, Sr) octahedra and cyclic P3O9 units, while alkali-metal atoms are located within the network. However, RbCdP3O9 and CsPbP(3)O(9)belong to the asymmetric space groups P (6) over bar c2 and Pna2(1) respectively, and the other three compounds belong to orthorhombic space group Pnma. Detailed structure comparisons in the M-I-M-II-P-O and ((MMP3O9)-M-I-P-II)(n) (n = 1, 2, 6) systems are discussed. Remarkably, KMgP3O9 as one of the cyclophosphate members exhibits a second harmonic generation (SHG) intensity about 0.2 times that of KH2PO4 (KDP), RbCdP3O9, and CsPbP3O9 also show SHG responses 0.1 times that of KDP. In addition, the related optical properties are discussed. Furthermore, theoretical calculations and dipole moments were calculated to explain the relation of structure and optical properties.

DOI10.1021/acs.inorgchem.8b01017
Indexed BySCI
WOS IDWOS:000436023800066
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5785
Collection中国科学院特殊环境功能材料与器件重点试验室
Corresponding AuthorHan, SJ (Han, Shujuan)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Abudoureheman, M ,Pan, XB ,Han, SJ ,et al. (MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties[J]. INORGANIC CHEMISTRY,2018,57(12):7372-7379.
APA Abudoureheman, M .,Pan, XB .,Han, SJ .,Rouzhahong, Y .,Yang, ZH .,...&Pan, SL .(2018).(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties.INORGANIC CHEMISTRY,57(12),7372-7379.
MLA Abudoureheman, M ,et al."(MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties".INORGANIC CHEMISTRY 57.12(2018):7372-7379.
Files in This Item:
File Name/Size DocType Version Access License
(MMP3O9)-M-I-P-II (M(3695KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Abudoureheman, M (Abudoureheman, Maierhaba)[ 1,2 ]]'s Articles
[Pan, XB (Pan, Xiaobo)[ 1 ]]'s Articles
[Han, SJ (Han, Shujuan)[ 1 ]]'s Articles
Baidu academic
Similar articles in Baidu academic
[Abudoureheman, M (Abudoureheman, Maierhaba)[ 1,2 ]]'s Articles
[Pan, XB (Pan, Xiaobo)[ 1 ]]'s Articles
[Han, SJ (Han, Shujuan)[ 1 ]]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Abudoureheman, M (Abudoureheman, Maierhaba)[ 1,2 ]]'s Articles
[Pan, XB (Pan, Xiaobo)[ 1 ]]'s Articles
[Han, SJ (Han, Shujuan)[ 1 ]]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: (MMP3O9)-M-I-P-II (M-I = Rb, M-II = Cd, Mg, Ca; M-I = Cs, M-II = Pb, Sr; M-I = K, M-II = Mg) Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties.pdf
Format: Adobe PDF
This file does not support browsing at this time
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.