Sn2B7O12F with a 2 1[ B14O24] 6-layer constructed from the unprecedented [ B7O16] 11-fundamental building block
Lu, ZX (Lu, Zixiu)[ 1,2,3,4 ]; Zhang, FF (Zhang, Fangfang)[ 1,2,3,4 ]; Tudi, A (Tudi, Abudukadi)[ 1,2,3,4 ]; Zhang, ZZ (Zhang, Zhizhong)[ 1,2,3,4 ]; Yang, ZH (Yang, Zhihua)[ 1,2,3,4 ]; Pan, SL (Pan, Shilie)[ 1,2,3,4 ]
2019
Source PublicationINORGANIC CHEMISTRY FRONTIERS
ISSN2052-1553
Volume6Issue:4Pages:996-1002
Abstract

A new tin borate fluoride Sn2B7O12F has been successfully synthesized by the high-temperature solution method in a closed system. It crystallizes in the monoclinic space group C2/c. The structure features a new fundamental building block (FBB) [B7O16](11-), which further condenses to an infinite 2[B14O24](6-) layer extended in the ab plane. The adjacent layers are bridged by the unique isolated [Sn4O12F2](18-) clusters, which are constructed from two [Sn2O7F](11-) polyhedra sharing a common edge. First-principles calculations have shown that the birefringence of Sn2B7O12F is about 0.07@1064 nm, which originated from the the synergistic contributions of the B-O and Sn-O/F interactions.

DOI10.1039/c9qi00120d
Indexed BySCI
WOS IDWOS:000468004900013
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5775
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)[ 1,2,3,4 ]
Affiliation1.CAS Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
4.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Lu, ZX ,Zhang, FF ,Tudi, A ,et al. Sn2B7O12F with a 2 1[ B14O24] 6-layer constructed from the unprecedented [ B7O16] 11-fundamental building block[J]. INORGANIC CHEMISTRY FRONTIERS,2019,6(4):996-1002.
APA Lu, ZX ,Zhang, FF ,Tudi, A ,Zhang, ZZ ,Yang, ZH ,&Pan, SL .(2019).Sn2B7O12F with a 2 1[ B14O24] 6-layer constructed from the unprecedented [ B7O16] 11-fundamental building block.INORGANIC CHEMISTRY FRONTIERS,6(4),996-1002.
MLA Lu, ZX ,et al."Sn2B7O12F with a 2 1[ B14O24] 6-layer constructed from the unprecedented [ B7O16] 11-fundamental building block".INORGANIC CHEMISTRY FRONTIERS 6.4(2019):996-1002.
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