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Diastereoselective alpha-Amination of N-tert-Butanesulfinyl Imidates Using N-Aryl-N-diphenylphosphinyldiazenes
Li, ZF (Li, Zheng-Fei)[ 1,3 ]; Yao, Y (Yao, Yun)[ 2 ]; Xu, YJ (Xu, Yan-Jun)[ 1 ]; Lu, CD (Lu, Chong-Dao)[ 1,2 ]
2019
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
ISSN0022-3263
Volume84Issue:11Pages:7207-7218
Abstract

Diastereoselective alpha-amination of N-tert-butanesulfinyl imidates has been developed using N-aryl (or N-tert-butyl) N-diphenylphosphinyldiazenes as nitrogen sources. The chiral 1-azaenolates derived from imidates undergo nucleophilic addition with diazenes to give alpha-hydrazino imidates in good yields.

DOI10.1021/acs.joc.9b00877
Indexed BySCI
WOS IDWOS:000471212000060
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5764
Collection省部共建新疆特有药用资源利用重点实验室
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China
2.Yunnan Univ, Sch Chem Sci & Technol, Kunming 650091, Yunnan, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Li, ZF ,Yao, Y ,Xu, YJ ,et al. Diastereoselective alpha-Amination of N-tert-Butanesulfinyl Imidates Using N-Aryl-N-diphenylphosphinyldiazenes[J]. JOURNAL OF ORGANIC CHEMISTRY,2019,84(11):7207-7218.
APA Li, ZF ,Yao, Y ,Xu, YJ ,&Lu, CD .(2019).Diastereoselective alpha-Amination of N-tert-Butanesulfinyl Imidates Using N-Aryl-N-diphenylphosphinyldiazenes.JOURNAL OF ORGANIC CHEMISTRY,84(11),7207-7218.
MLA Li, ZF ,et al."Diastereoselective alpha-Amination of N-tert-Butanesulfinyl Imidates Using N-Aryl-N-diphenylphosphinyldiazenes".JOURNAL OF ORGANIC CHEMISTRY 84.11(2019):7207-7218.
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