Ba4M(CO3)(2)(BO3)(2) (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method
Zhang, XY (Zhang, Xueyan)[ 1 ]; Wu, HP (Wu, Hongping)[ 1 ]; Yu, HW (Yu, Hongwei)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
2019
Source PublicationSCIENCE CHINA-MATERIALS
ISSN2095-8226
Volume62Issue:7Pages:1023-1032
Abstract

Two borate-carbonates Ba4M(CO3)(2)(BO3)(2) (M = Ba, Sr) have been successfully synthesized in the open air representing the first examples of borate-carbnate complex. Their structures were determined by single crystal X-ray diffraction and they both crystallize in same space group, Pnma. Their structures feature a Ba/Sr-based three dimensional framework composed of the BaO8 polyhedra (the SrO8 polyhedra), isolated BO3 and CO3 triangles. Detailed structure analysis shows that the intergrowth of [Ba-3(BO3)(2)]/[Ba2Sr(BO3)(2)] and [BaCO3] layers favors the formation of these two borate-carbonates. In addition, their syntheses, spectroscopic properties and thermal behaviors were investigated.

Keywordborate-carbonates open air intergrowth
DOI10.1007/s40843-018-9390-2
Indexed BySCI
WOS IDWOS:000467276500012
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5753
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)[ 1 ]
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Zhang, XY ,Wu, HP ,Yu, HW ,et al. Ba4M(CO3)(2)(BO3)(2) (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method[J]. SCIENCE CHINA-MATERIALS,2019,62(7):1023-1032.
APA Zhang, XY ,Wu, HP ,Yu, HW ,Yang, ZH ,&Pan, SL .(2019).Ba4M(CO3)(2)(BO3)(2) (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method.SCIENCE CHINA-MATERIALS,62(7),1023-1032.
MLA Zhang, XY ,et al."Ba4M(CO3)(2)(BO3)(2) (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method".SCIENCE CHINA-MATERIALS 62.7(2019):1023-1032.
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