The First Examples of Lithium-Containing Mixed-Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges
Ma, RR (Ma, Ruru)[ 1,2 ]; Yang, Y (Yang, Yun)[ 1 ]; Hu, C (Hu, Cong)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
2018
发表期刊CHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
卷号24期号:57页码:15355-15364
摘要

Three new mixed-alkali strontium borates, Li2KSr6(BO3)(5), Li2Rb7Sr24(BO3)(19), and Li2Rb2SrB18O30, have been synthesized by the high-temperature solution method by adjusting the molar ratios of the reactants. They represent the first examples of lithium-containing mixed-alkali strontium borates. The structures of the three compounds show different dimensional anionic architectures, with Li2KSr6(BO3)(5) and Li2Rb7Sr24(BO3)(19) possessing isolated BO3 units, whereas Li2Rb2SrB18O30 has three-dimensional (3D) (3)(infinity)[B9O15](3-) open frameworks with three types of channels occupied by the strontium and rubidium atoms. Interestingly, Li2KSr6(BO3)(5) is the first example of a (1)(infinity)[Li2O7](12-) chain composed of LiO5 linked through the sharing of vertexes and edges. However, in Li2Rb7Sr24(BO3)(19), isolated LiO3 units can be observed, which is also rare in borates. Detailed analysis and comparisons of the structures of the anhydrous mixed-alkali- and alkaline-earth-metal borates and nine-polymeric fundamental building blocks have been made. Furthermore, Li2Rb7Sr24(BO3)(19) and Li2Rb2SrB18O30 present short cutoff edges (< 190 nm), which was confirmed by the UV/Vis/NIR diffuse reflectance spectra. These attributes make them attractive for deep-UV optical materials.

关键词Alkali Metals Borates Density Functional Calculations Strontium Structure Elucidation
DOI10.1002/chem.201803325
收录类别SCI
WOS记录号WOS:000447124800030
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5613
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Pan, SL (Pan, Shilie)[ 1 ]
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Functioal Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Univ, Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ma, RR ,Yang, Y ,Hu, C ,et al. The First Examples of Lithium-Containing Mixed-Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(57):15355-15364.
APA Ma, RR ,Yang, Y ,Hu, C ,Yang, ZH ,&Pan, SL .(2018).The First Examples of Lithium-Containing Mixed-Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges.CHEMISTRY-A EUROPEAN JOURNAL,24(57),15355-15364.
MLA Ma, RR ,et al."The First Examples of Lithium-Containing Mixed-Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges".CHEMISTRY-A EUROPEAN JOURNAL 24.57(2018):15355-15364.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
The First Examples o(1599KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Ma, RR (Ma, Ruru)[ 1,2 ]]的文章
[Yang, Y (Yang, Yun)[ 1 ]]的文章
[Hu, C (Hu, Cong)[ 1,2 ]]的文章
百度学术
百度学术中相似的文章
[Ma, RR (Ma, Ruru)[ 1,2 ]]的文章
[Yang, Y (Yang, Yun)[ 1 ]]的文章
[Hu, C (Hu, Cong)[ 1,2 ]]的文章
必应学术
必应学术中相似的文章
[Ma, RR (Ma, Ruru)[ 1,2 ]]的文章
[Yang, Y (Yang, Yun)[ 1 ]]的文章
[Hu, C (Hu, Cong)[ 1,2 ]]的文章
相关权益政策
暂无数据
收藏/分享
文件名: The First Examples of Lithium-Containing Mixed-Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。