Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn)
Chu, Y (Chu, Yu)[ 1,2,3 ]; Wu, K (Wu, Kui)[ 1,2 ]; Su, X (Su, Xin)[ 1,2 ]; Han, J (Han, Jian)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1,2 ]
2018
发表期刊INORGANIC CHEMISTRY
ISSN0020-1669
卷号57期号:18页码:11310-11313
摘要

A suite of quinary thiohalides, ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn), have been successfully synthesized. ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn) undergoes an interesting structural transition from P2(1)/c (alpha phase) to I4/mcm (beta phase), which also leads to obvious disparities on the birefringence from 0.041 (alpha phase) to 0.094 (beta phase). Moreover, the result of deploying a real-space atom-cutting method on ABa(2)MS(4)Cl reveals that their (MS4)(4-) groups may take the major effect in terms of the anisotropy by a structural transition.

DOI10.1021/acs.inorgchem.8b01788
收录类别SCI
WOS记录号WOS:000445165400003
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5593
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Pan, SL (Pan, Shilie)[ 1,2 ]
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Chu, Y ,Wu, K ,Su, X ,et al. Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn)[J]. INORGANIC CHEMISTRY,2018,57(18):11310-11313.
APA Chu, Y ,Wu, K ,Su, X ,Han, J ,Yang, ZH ,&Pan, SL .(2018).Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn).INORGANIC CHEMISTRY,57(18),11310-11313.
MLA Chu, Y ,et al."Intriguing Structural Transition Inducing Variable Birefringences in ABa(2)MS(4)Cl (A = Rb, Cs; M = Ge, Sn)".INORGANIC CHEMISTRY 57.18(2018):11310-11313.
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