Two noncentrosymmetric polyphosphates featuring infinite one-dimensional (PO3)(infinity), chain, LiMP2O6 (M = Rb, Cs): Synthesis, structure and optical properties
Baiheti, T (Baiheti, Tuohetijiang)[ 1,2 ]; Li, H (Li, Hao)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Han, SJ (Han, Shujuan)[ 1 ]; Wang, Y (Wang, Ying)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
2018
发表期刊JOURNAL OF SOLID STATE CHEMISTRY
ISSN0022-4596
卷号266期号:10页码:150-154
摘要

Two noncentrosymmetric polyphosphates, namely LiCsP2O6 and LiRbP2O6 have been synthesized from the high temperature solution. The structural analysis suggests that both of them crystallize in orthorhombic space group Fdd2 (No.43), with lattice parameters: a = 18.517(4) angstrom, b = 19.037(4) angstrom, c = 13.011(3) A, and Z= 32 for LiRbP2O6, while a = 19.009(13) angstrom, b = 19.402(13)angstrom, c= 13.180(9) angstrom, and Z = 32 for LiCsP2O6. In the structure, the PO4 polyhedra are connected through corner -sharing to form 10 infinite (PO3) co chains stretching along the c axis, which are further linked by the LiO4 polyhedra to construct a 3D framework with two types of tunnels. And the Rb/Cs atoms are filled in or around the periphery of the tunnels to keep the charge equilibrium. The IR spectra verify their structural validity. In addition, other characterizations including the UV-vis-NIR diffuse reflectance spectra, as well as first -principles theoretical studies have been performed on the two compounds.

关键词Polyphosphates Structural Analysis X-ray Diffraction Theoretical Calculations
DOI10.1016/j.jssc.2018.07.015
收录类别SCI
WOS记录号WOS:000444664800019
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5592
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Han, SJ (Han, Shujuan)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Baiheti, T ,Li, H ,Yang, ZH ,et al. Two noncentrosymmetric polyphosphates featuring infinite one-dimensional (PO3)(infinity), chain, LiMP2O6 (M = Rb, Cs): Synthesis, structure and optical properties[J]. JOURNAL OF SOLID STATE CHEMISTRY,2018,266(10):150-154.
APA Baiheti, T ,Li, H ,Yang, ZH ,Han, SJ ,Wang, Y ,&Pan, SL .(2018).Two noncentrosymmetric polyphosphates featuring infinite one-dimensional (PO3)(infinity), chain, LiMP2O6 (M = Rb, Cs): Synthesis, structure and optical properties.JOURNAL OF SOLID STATE CHEMISTRY,266(10),150-154.
MLA Baiheti, T ,et al."Two noncentrosymmetric polyphosphates featuring infinite one-dimensional (PO3)(infinity), chain, LiMP2O6 (M = Rb, Cs): Synthesis, structure and optical properties".JOURNAL OF SOLID STATE CHEMISTRY 266.10(2018):150-154.
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