A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species
Han, GP (Han, Guopeng)[ 1,2 ]; Lei, BH (Lei, Bing-Hua)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Wang, Y (Wang, Ying)[ 1 ]; Pan, Sl (Pan, Shilie)[ 1 ]
2018
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
Volume57Issue:31Pages:9828-9832
Abstract

The large number and structural beauty of silicates are largely due to the variety of connection mode of SiO4 tetrahedra. SiO6 and SiF6 octahedra are also known and give rise for structural versatility of inorganic silicates. However, to date, the crystal structure of inorganic fluorooxosilicates with oxofluoride SiOxF4-x or SiOxF6-x species are unknown. Now, fluorine was successfully introduced into the silicophosphates, and the first fluorooxosilicophosphate K4Si3P2O7F12 with an unprecedented SiO2F4 species was synthesized. The existence of Si-F bonds was verified by comprehensively experimental and theoretical work. Using ab initio and bond valence calculations, the oxofluoride SiOxF6-x species is shown to be stable when oxygen atoms connect to other atoms with strong covalent interactions. This work will contribute to the structural diversity of silicate chemistry by the exploration of the new fluorooxosilicates.

KeywordFluorine Fluorooxosilicates Silicon Solid-state Nmr Structure Elucidation
DOI10.1002/anie.201805759
Indexed BySCI
WOS IDWOS:000439741900043
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5585
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, Sl (Pan, Shilie)[ 1 ]
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Han, GP ,Lei, BH ,Yang, ZH ,et al. A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(31):9828-9832.
APA Han, GP ,Lei, BH ,Yang, ZH ,Wang, Y ,&Pan, Sl .(2018).A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(31),9828-9832.
MLA Han, GP ,et al."A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.31(2018):9828-9832.
Files in This Item:
File Name/Size DocType Version Access License
A Fluorooxosilicopho(1747KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Han, GP (Han, Guopeng)[ 1,2 ]]'s Articles
[Lei, BH (Lei, Bing-Hua)[ 1,2 ]]'s Articles
[Yang, ZH (Yang, Zhihua)[ 1 ]]'s Articles
Baidu academic
Similar articles in Baidu academic
[Han, GP (Han, Guopeng)[ 1,2 ]]'s Articles
[Lei, BH (Lei, Bing-Hua)[ 1,2 ]]'s Articles
[Yang, ZH (Yang, Zhihua)[ 1 ]]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Han, GP (Han, Guopeng)[ 1,2 ]]'s Articles
[Lei, BH (Lei, Bing-Hua)[ 1,2 ]]'s Articles
[Yang, ZH (Yang, Zhihua)[ 1 ]]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: A Fluorooxosilicophosphate with an Unprecedented SiO2F4 Species.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.