K3B6O9F3: A New Fluorooxoborate with Four Different Anionic Units
Han, GP (Han, Guopeng)[ 1,2 ]; Shi, GQ (Shi, Guoqiang)[ 1,2 ]; Wang, Y (Wang, Ying)[ 1 ]; Zhang, BB (Zhang, Bingbing)[ 1 ]; Han, SJ (Han, Shujuan)[ 1 ]; Zhang, FF (Zhang, Fangfang)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
2018
发表期刊CHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
卷号24期号:18页码:4497-4502
摘要

K3B6O9F3, a first fluorooxoborate containing four different units, that is, [BO3](3-), [BO4](5-), [BO3F](4-), and [BO2F2](3-), has been designed and synthesized by two different routes. The unique anionic [B6O9F3](3-) layers avoid forming terminal oxygen atoms, which are beneficial to enlarge the band gap. The structure-properties relationship of the title compound is discussed.

关键词Deep-ultraviolet Fluorooxoborate Fundamental Building Block Synthesis
DOI10.1002/chem.201705751
收录类别SCI
WOS记录号WOS:000428378300004
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5584
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Zhang, FF (Zhang, Fangfang)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
作者单位1.CAS Xinjiang Key Lab Elect Informat Mat & Devices, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Han, GP ,Shi, GQ ,Wang, Y ,et al. K3B6O9F3: A New Fluorooxoborate with Four Different Anionic Units[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(18):4497-4502.
APA Han, GP .,Shi, GQ .,Wang, Y .,Zhang, BB .,Han, SJ .,...&Pan, SL .(2018).K3B6O9F3: A New Fluorooxoborate with Four Different Anionic Units.CHEMISTRY-A EUROPEAN JOURNAL,24(18),4497-4502.
MLA Han, GP ,et al."K3B6O9F3: A New Fluorooxoborate with Four Different Anionic Units".CHEMISTRY-A EUROPEAN JOURNAL 24.18(2018):4497-4502.
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