Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates
Zhang, BB (Zhang, Bingbing)[ 1 ]; Han, GP (Han, Guopeng)[ 1,2 ]; Wang, Y (Wang, Ying)[ 1 ]; Chen, XL (Chen, Xinglong)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
2018
发表期刊CHEMISTRY OF MATERIALS
ISSN0897-4756
卷号32期号:15页码:5397-5403
摘要

If a bucket is to hold more water, its shortest plank must be made longer. This guideline also applies to the exploration of ultraviolet (UV) and deep-UV (DUV) nonlinear optical (NLO) materials that are limited by multiple criteria. Phosphates are one kind of promising candidate for new NLO materials. Unfortunately, the small birefringence, as the shortest plank, severely restricts the phase-matching of second harmonic generation (SHG) in the UV/DUV region. In this work, fluorophosphates are rationally proposed as substitutes for phosphates to break down the limitation of birefringence and simultaneously enhance SHG response and retain wide UV transmittance. The (PO3F)(2-) and (PO2F2)(-) groups are confirmed as superior material genomes to achieve the discussed combination properties. Accordingly, (NH4)(2)PO3F was screened out by density functional theory calculation, and single crystals with centimeter size have been grown. It possesses a powder SHG efficiency of 1 x KH2PO4 (KDP) and is phase-matchable with output of SHG wavelength at 266 nm. To the best of our knowledge, it is the first time that fluorophosphates are identified and developed as new and ideal candidates to new UV/DUV NLO materials by combining theories and experiments.

DOI10.1021/acs.chemmater.8b02223
收录类别SCI
WOS记录号WOS:000442186500059
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5583
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
作者单位1.Chinese Acad Sci, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Zhang, BB ,Han, GP ,Wang, Y ,et al. Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates[J]. CHEMISTRY OF MATERIALS,2018,32(15):5397-5403.
APA Zhang, BB ,Han, GP ,Wang, Y ,Chen, XL ,Yang, ZH ,&Pan, SL .(2018).Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates.CHEMISTRY OF MATERIALS,32(15),5397-5403.
MLA Zhang, BB ,et al."Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates".CHEMISTRY OF MATERIALS 32.15(2018):5397-5403.
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