K2TeP2O8: a new telluro-phosphate with a pentagonal Te-P-O layer structure
Wen, M (Wen, Ming)[ 1 ]; Hu, C (Hu, Cong)[ 2 ]; Yang, ZH (Yang, Zhihua)[ 2 ]; Wu, XH (Wu, Xiaohong)[ 1 ]; Pan, SL (Pan, Shilie)[ 1,2 ]
2018
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume47Issue:28Pages:9453-9458
Abstract

A new telluro-phosphate K2TeP2O8 was synthesized by a high temperature solution method. It crystallizes in the orthorhombic space group P2(1)2(1)2 and features a [TeP2O8](2-) layer structure, which is the first layer structure built by Te-O and P-O groups among the telluro-phosphates. More interestingly, the layer structure in K2TeP2O8 is nearly pentagonal. First-principles theoretical calculations suggest that K2TeP2O8 possesses a large birefringence compared to phosphates. Furthermore, IR spectra, UV-vis-NIR diffuse reflectance spectroscopy data, thermal behavior, and electronic structure calculations were studied.

DOI10.1039/c8dt01576g
Indexed BySCI
WOS IDWOS:000444187700028
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5572
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)[ 1,2 ]
Affiliation1.Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Wen, M ,Hu, C ,Yang, ZH ,et al. K2TeP2O8: a new telluro-phosphate with a pentagonal Te-P-O layer structure[J]. DALTON TRANSACTIONS,2018,47(28):9453-9458.
APA Wen, M ,Hu, C ,Yang, ZH ,Wu, XH ,&Pan, SL .(2018).K2TeP2O8: a new telluro-phosphate with a pentagonal Te-P-O layer structure.DALTON TRANSACTIONS,47(28),9453-9458.
MLA Wen, M ,et al."K2TeP2O8: a new telluro-phosphate with a pentagonal Te-P-O layer structure".DALTON TRANSACTIONS 47.28(2018):9453-9458.
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