Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials
Lei, BH (Lei, Bing-Hua)[ 1,2,3 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ]; Yu, HW (Yu, Hongwei)[ 1,2 ]; Cao, C (Cao, Chao)[ 4 ]; Li, Z (Li, Zhi)[ 1,2 ]; Hu, C (Hu, Cong)[ 1,2,3 ]; Poeppelmeier, KR (Poeppelmeier, Kenneth R.)[ 5 ]; Pan, SL (Pan, Shilie)[ 1,2 ]
2018
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume140Issue:34Pages:10726-10733
Abstract

Design of functional materials with targeted properties is a challenge because of the diversity of their potential structures. The functional performances of materials are mainly determined by the chemistry and electronic structure of modules consisting of local atomic groups with special arrangements. Tetrahedral modules are excellent modules for designing deep-ultraviolet/ultraviolet (UV) nonlinear optical (NLO) materials, but they are rarely favored due to their unpredictable optical anisotropy and second harmonic generation (SHG) response. In this work, we have developed a module-guided ab initio approach for evaluating the optical anisotropy of tetrahedral modules. The application of this method indicates that the tetrahedral modules with a specific arrangement will enhance the optical anisotropy of materials. With the functional modules consisting of tetrahedral modules and rare-earth cations, new high-performance rare-earth phosphates were assembled. These materials are promising deep-UV NLO materials because of their appropriate birefringences, large band gaps, moderate SHG responses, and easy to obtain large size crystals.

DOI10.1021/jacs.8b03057
Indexed BySCI
WOS IDWOS:000443654400019
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5556
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorYang, ZH (Yang, Zhihua)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1,2 ]
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Beijing, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Hangzhou Normal Univ, Dept Phys, Condensed Matter Grp, Hangzhou 310036, Zhejiang, Peoples R China
5.Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
Recommended Citation
GB/T 7714
Lei, BH ,Yang, ZH ,Yu, HW ,et al. Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018,140(34):10726-10733.
APA Lei, BH .,Yang, ZH .,Yu, HW .,Cao, C .,Li, Z .,...&Pan, SL .(2018).Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(34),10726-10733.
MLA Lei, BH ,et al."Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.34(2018):10726-10733.
Files in This Item:
File Name/Size DocType Version Access License
Module-Guided Design(2084KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Lei, BH (Lei, Bing-Hua)[ 1,2,3 ]]'s Articles
[Yang, ZH (Yang, Zhihua)[ 1,2 ]]'s Articles
[Yu, HW (Yu, Hongwei)[ 1,2 ]]'s Articles
Baidu academic
Similar articles in Baidu academic
[Lei, BH (Lei, Bing-Hua)[ 1,2,3 ]]'s Articles
[Yang, ZH (Yang, Zhihua)[ 1,2 ]]'s Articles
[Yu, HW (Yu, Hongwei)[ 1,2 ]]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Lei, BH (Lei, Bing-Hua)[ 1,2,3 ]]'s Articles
[Yang, ZH (Yang, Zhihua)[ 1,2 ]]'s Articles
[Yu, HW (Yu, Hongwei)[ 1,2 ]]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.