PtIx/[(CH3)(2)NH2](3)[BiI6] as a well-dispersed photocatalyst for hydrogen production in hydroiodic acid
Zhao, H (Zhao, He); Li, YX (Li, Yingxuan); Zhang, B (Zhang, Bing); Xu, T (Xu, Tao)[ 5 ]; Wang, CY (Wang, Chuanyi)
2018
发表期刊NANO ENERGY
ISSN2211-2855
卷号50期号:8页码:665-674
摘要

Constructing a photocatalytic system for hydrogen generation is a promising means for producing clean and renewable energy. However, developing photocatalysts with high efficiency in a wide range of visible light is still a formidable challenge. Here, we report on a highly active system for photocatalytic hydrogen production from hydroiodic acid splitting that contains a soluble organic-inorganic hybrid PtIx/[(CH3)(2)NH2](3)[BiI6] as a newcomer photocatalyst for harvesting a wide range of visible light (up to 630 nm). Under irradiation at 465 nm, the photocatalytic system achieves apparent quantum yield of similar to 82.8% for photocatalytic hydrogen production along with a stable activity for at least 100 h. We propose that the superior photocatalytic performance is attributed to collisions between [BiI6](3)(-) and Pt ions (Pt2+ or Pt4+), giving rise to efficient charge separation, which could be an effective approach towards designing and fabricating organic-inorganic semiconductors with improved performance in photocatalysis.

关键词Ptix/[(Ch3)(2)Nh2](3)[Bii6] Well-dispersed Photocatalyst Hi Splitting H-2 Production Visible Light
DOI10.1016/j.nanoen.2018.06.033
收录类别SCI
WOS记录号WOS:000438076200077
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5518
专题中国科学院特殊环境功能材料与器件重点试验室
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
3.Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Shaanxi, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Northern Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA
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Zhao, H ,Li, YX ,Zhang, B ,et al. PtIx/[(CH3)(2)NH2](3)[BiI6] as a well-dispersed photocatalyst for hydrogen production in hydroiodic acid[J]. NANO ENERGY,2018,50(8):665-674.
APA Zhao, H ,Li, YX ,Zhang, B ,Xu, T ,&Wang, CY .(2018).PtIx/[(CH3)(2)NH2](3)[BiI6] as a well-dispersed photocatalyst for hydrogen production in hydroiodic acid.NANO ENERGY,50(8),665-674.
MLA Zhao, H ,et al."PtIx/[(CH3)(2)NH2](3)[BiI6] as a well-dispersed photocatalyst for hydrogen production in hydroiodic acid".NANO ENERGY 50.8(2018):665-674.
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