NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers
Huang, CM (Huang, Chunmei); Zhang, FF (Zhang, Fangfang); Zhang, BB (Zhang, Bingbing); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2018
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume42Issue:14Pages:12091-12097
Abstract

The ammonium borate NH4B11O16(OH)(2) has been successfully synthesized by a mild hydrothermal method. Its structure features a new fundamental building block (FBB) [B11O18(OH)(2)], which is composed of a [B5O10] double-ring and two [B3O5(OH)] single-rings via sharing corner oxygen atoms. The FBB further condenses into 2D wavy-shaped polycyclic layers 2[B11O16(OH)(2)] and forms the final framework through hydrogen bonding. Specifically, the effect of the hydroxyl to boron ratio (N-OH/N-B) on the FBB assembly has been investigated in the ammonium borate system. In addition, the optical and thermal properties of this compound have been studied experimentally. First-principles calculations have also been carried out in order to understand the electronic structure.

DOI10.1039/c8nj02359j
Indexed BySCI
WOS IDWOS:000438394800102
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Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5515
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, FF (Zhang, Fangfang); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Huang, CM ,Zhang, FF ,Zhang, BB ,et al. NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers[J]. NEW JOURNAL OF CHEMISTRY,2018,42(14):12091-12097.
APA Huang, CM ,Zhang, FF ,Zhang, BB ,Yang, ZH ,&Pan, SL .(2018).NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers.NEW JOURNAL OF CHEMISTRY,42(14),12091-12097.
MLA Huang, CM ,et al."NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers".NEW JOURNAL OF CHEMISTRY 42.14(2018):12091-12097.
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