NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers
Huang, CM (Huang, Chunmei); Zhang, FF (Zhang, Fangfang); Zhang, BB (Zhang, Bingbing); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2018
发表期刊NEW JOURNAL OF CHEMISTRY
ISSN1144-0546
卷号42期号:14页码:12091-12097
摘要

The ammonium borate NH4B11O16(OH)(2) has been successfully synthesized by a mild hydrothermal method. Its structure features a new fundamental building block (FBB) [B11O18(OH)(2)], which is composed of a [B5O10] double-ring and two [B3O5(OH)] single-rings via sharing corner oxygen atoms. The FBB further condenses into 2D wavy-shaped polycyclic layers 2[B11O16(OH)(2)] and forms the final framework through hydrogen bonding. Specifically, the effect of the hydroxyl to boron ratio (N-OH/N-B) on the FBB assembly has been investigated in the ammonium borate system. In addition, the optical and thermal properties of this compound have been studied experimentally. First-principles calculations have also been carried out in order to understand the electronic structure.

DOI10.1039/c8nj02359j
收录类别SCI
WOS记录号WOS:000438394800102
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5515
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Zhang, FF (Zhang, Fangfang); Pan, SL (Pan, Shilie)
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Huang, CM ,Zhang, FF ,Zhang, BB ,et al. NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers[J]. NEW JOURNAL OF CHEMISTRY,2018,42(14):12091-12097.
APA Huang, CM ,Zhang, FF ,Zhang, BB ,Yang, ZH ,&Pan, SL .(2018).NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers.NEW JOURNAL OF CHEMISTRY,42(14),12091-12097.
MLA Huang, CM ,et al."NH4B11O16(OH)(2): a new ammonium borate with wavy-shaped polycyclic 2[B11O16(OH)(2)] layers".NEW JOURNAL OF CHEMISTRY 42.14(2018):12091-12097.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
NH4B11O16(OH)2 a new(2255KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Huang, CM (Huang, Chunmei)]的文章
[Zhang, FF (Zhang, Fangfang)]的文章
[Zhang, BB (Zhang, Bingbing)]的文章
百度学术
百度学术中相似的文章
[Huang, CM (Huang, Chunmei)]的文章
[Zhang, FF (Zhang, Fangfang)]的文章
[Zhang, BB (Zhang, Bingbing)]的文章
必应学术
必应学术中相似的文章
[Huang, CM (Huang, Chunmei)]的文章
[Zhang, FF (Zhang, Fangfang)]的文章
[Zhang, BB (Zhang, Bingbing)]的文章
相关权益政策
暂无数据
收藏/分享
文件名: NH4B11O16(OH)2 a new ammonium borate with wavy-shaped polycyclic 2∞[B11O16(OH)2] layers.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。