MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges
Chen, XL (Chen, Xinglong); Zhang, FF (Zhang, Fangfang); Shi, YJ (Shi, Yunjing); Sun, YZ (Sun, Yanzhou); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2018
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume47Issue:3Pages:750-757
Abstract

Two new rare-earth borates, MBaYB6O12 (M = Rb, Cs), which are the first reported compounds in M2O-BaO-RE2O3-B2O3 (M = Rb, Cs; RE = rare-earth) quaternary systems, have been discovered through a high-temperature solution method and their structures were determined by single-crystal X-ray diffraction. These two compounds are isostructural with the centrosymmetric space group R (3) over bar (no. 148) and the fundamental building blocks are the B3O6 groups which are nearly parallel to each other. The spectral measurement shows that the cutoff edges of the two compounds are all down to the deep-ultraviolet (deep-UV) region (below 200 nm). And the experimental birefringence of RbBaYB6O12 and RbBaYB6O12 is about 0.12 at 589 nm. Moreover, first-principles theoretical studies were carried out to gain a better understanding of the structure-property relationships. The calculation results demonstrate that both the compounds have a large birefringence of 0.100 at 589 nm, which corresponds to the experimental value. Both experimental and theoretical studies suggest that MBaYB6O12 (M = Rb, Cs) are potential birefringent materials for UV and deep-UV applications.

DOI10.1039/c7dt04223j
Indexed BySCI
WOS IDWOS:000422643800018
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5506
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, FF (Zhang, Fangfang); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Xinjiang Inst Engn, Dept Chem & Environm Engn, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Chen, XL ,Zhang, FF ,Shi, YJ ,et al. MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges[J]. DALTON TRANSACTIONS,2018,47(3):750-757.
APA Chen, XL ,Zhang, FF ,Shi, YJ ,Sun, YZ ,Yang, ZH ,&Pan, SL .(2018).MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges.DALTON TRANSACTIONS,47(3),750-757.
MLA Chen, XL ,et al."MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges".DALTON TRANSACTIONS 47.3(2018):750-757.
Files in This Item:
File Name/Size DocType Version Access License
MBaYB6O12 (M = Rb, C(1243KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Chen, XL (Chen, Xinglong)]'s Articles
[Zhang, FF (Zhang, Fangfang)]'s Articles
[Shi, YJ (Shi, Yunjing)]'s Articles
Baidu academic
Similar articles in Baidu academic
[Chen, XL (Chen, Xinglong)]'s Articles
[Zhang, FF (Zhang, Fangfang)]'s Articles
[Shi, YJ (Shi, Yunjing)]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Chen, XL (Chen, Xinglong)]'s Articles
[Zhang, FF (Zhang, Fangfang)]'s Articles
[Shi, YJ (Shi, Yunjing)]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: MBaYB6O12 (M = Rb, Cs) two new rare-earth borates with large birefringence and short ultraviolet cutoff edges.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.