MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges
Chen, XL (Chen, Xinglong); Zhang, FF (Zhang, Fangfang); Shi, YJ (Shi, Yunjing); Sun, YZ (Sun, Yanzhou); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie); Zhang, FF; Pan, SL
2018
发表期刊DALTON TRANSACTIONS
卷号47期号:3页码:750-757
摘要

Two new rare-earth borates, MBaYB6O12 (M = Rb, Cs), which are the first reported compounds in M2O-BaO-RE2O3-B2O3 (M = Rb, Cs; RE = rare-earth) quaternary systems, have been discovered through a high-temperature solution method and their structures were determined by single-crystal X-ray diffraction. These two compounds are isostructural with the centrosymmetric space group R (3) over bar (no. 148) and the fundamental building blocks are the B3O6 groups which are nearly parallel to each other. The spectral measurement shows that the cutoff edges of the two compounds are all down to the deep-ultraviolet (deep-UV) region (below 200 nm). And the experimental birefringence of RbBaYB6O12 and RbBaYB6O12 is about 0.12 at 589 nm. Moreover, first-principles theoretical studies were carried out to gain a better understanding of the structure-property relationships. The calculation results demonstrate that both the compounds have a large birefringence of 0.100 at 589 nm, which corresponds to the experimental value. Both experimental and theoretical studies suggest that MBaYB6O12 (M = Rb, Cs) are potential birefringent materials for UV and deep-UV applications.

DOI10.1039/c7dt04223j
收录类别SCI
WOS记录号WOS:000422643800018
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5506
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Zhang, FF; Pan, SL
作者单位1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Xinjiang Inst Engn, Dept Chem & Environm Engn, Urumqi 830011, Peoples R China
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GB/T 7714
Chen, XL ,Zhang, FF ,Shi, YJ ,et al. MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges[J]. DALTON TRANSACTIONS,2018,47(3):750-757.
APA Chen, XL .,Zhang, FF .,Shi, YJ .,Sun, YZ .,Yang, ZH .,...&Pan, SL.(2018).MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges.DALTON TRANSACTIONS,47(3),750-757.
MLA Chen, XL ,et al."MBaYB6O12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges".DALTON TRANSACTIONS 47.3(2018):750-757.
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