SiO2-supported Co-Rh bimetallic catalysts for dicyclopentadiene hydroformylation: relationships between catalytic performance and structure of the catalysts
Zhang, LB (Zhang, Libo); Li, CY (Li, Chengyang); Ma, YB (Ma, Yubo); Wang, TF (Wang, Tianfu)
2018
发表期刊PROGRESS IN REACTION KINETICS AND MECHANISM
ISSN1468-6783
卷号43期号:2页码:136-143
摘要

In this work, SiO2-supported Co-Rh bimetallic catalysts were prepared by adopting a method of impregnation and were used to catalyse the hydroformylation of dicyclopentadiene (DCPD) to diformyltricyclodecanes. Firstly, the hydroformylation of DCPD was carried out and three reaction stages were observed. In the first stage, a sharp decrease of reaction pressure was observed within 4 minutes. In the next stage, almost no reaction pressure decrease was detected over a relatively longer reaction time (70 minutes). In the final stage, the reaction pressure decreased at a relatively gentle rate, with barely any decrease of reaction pressure being observed at 460 minutes. Secondly, the hydroformylation of monoformyltricyclodecenes (MFTD) with various reaction times was carried out; the catalyst that was used at various reaction times was also recovered. Finally, the catalyst that had been used at various reaction times was characterised and analysed and the relationship between the catalytic performance and the structure of the catalysts was confirmed. In addition, combined with triphenylphosphine, the influence of pressure on the activity of Co-Rh bimetallic catalysts was investigated for the hydroformylation of MFTD.

关键词Dicyclopentadiene Hydroformylation Monoformyltricyclodecenes Diformyltricyclodecanes Co-rh Bimetallic Catalyst Structure-reactivity Relation
DOI10.3184/146867818X15161889114475
收录类别SCI
WOS记录号WOS:000436453500004
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5481
专题中国科学院特殊环境功能材料与器件重点试验室
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, LB ,Li, CY ,Ma, YB ,et al. SiO2-supported Co-Rh bimetallic catalysts for dicyclopentadiene hydroformylation: relationships between catalytic performance and structure of the catalysts[J]. PROGRESS IN REACTION KINETICS AND MECHANISM,2018,43(2):136-143.
APA Zhang, LB ,Li, CY ,Ma, YB ,&Wang, TF .(2018).SiO2-supported Co-Rh bimetallic catalysts for dicyclopentadiene hydroformylation: relationships between catalytic performance and structure of the catalysts.PROGRESS IN REACTION KINETICS AND MECHANISM,43(2),136-143.
MLA Zhang, LB ,et al."SiO2-supported Co-Rh bimetallic catalysts for dicyclopentadiene hydroformylation: relationships between catalytic performance and structure of the catalysts".PROGRESS IN REACTION KINETICS AND MECHANISM 43.2(2018):136-143.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
SiO2-supported Co-Rh(1853KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhang, LB (Zhang, Libo)]的文章
[Li, CY (Li, Chengyang)]的文章
[Ma, YB (Ma, Yubo)]的文章
百度学术
百度学术中相似的文章
[Zhang, LB (Zhang, Libo)]的文章
[Li, CY (Li, Chengyang)]的文章
[Ma, YB (Ma, Yubo)]的文章
必应学术
必应学术中相似的文章
[Zhang, LB (Zhang, Libo)]的文章
[Li, CY (Li, Chengyang)]的文章
[Ma, YB (Ma, Yubo)]的文章
相关权益政策
暂无数据
收藏/分享
文件名: SiO2-supported Co-Rh bimetallic catalysts for dicyclopentadiene hydroformylation relationships between catalytic performance and structure of the catalysts.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。