CaB5O7F3: A Beryllium-Free Alkaline-Earth Fluorooxoborate Exhibiting Excellent Nonlinear Optical Performances
Zhang, ZZ (Zhang, Zhizhong); Wang, Y (Wang, Ying); Zhang, BB (Zhang, Bingbing); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2018
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume57Issue:9Pages:4820-4823
Abstract

Noncentrosymmetric (NCS) fluorooxoborates are one of the most attractive systems for discovering the new deep-ultraviolet (DUV) nonlinear optical (NLO) materials. Here, we report the formation, crystal structure, and optical properties of a new NCS alkaline earth fluorooxoborate: CaB5O7F3. It exhibits excellent NLO performances including large band gap (8.75 eV), large second harmonic generation intensity (2 x KH2PO4 and 0.4 x beta-BaB2O4, under 1064 and 532 nm radiation, respectively), and moderate birefringence (0.07 @ 1064 nm) that enables frequency doubling down to 183 nm. It demonstrates that CaB5O7F3 is a promising DUV NLO material.

DOI10.1021/acs.inorgchem.8b00531
Indexed BySCI
WOS IDWOS:000431833500009
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5407
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorWang, Y (Wang, Ying); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang, ZZ ,Wang, Y ,Zhang, BB ,et al. CaB5O7F3: A Beryllium-Free Alkaline-Earth Fluorooxoborate Exhibiting Excellent Nonlinear Optical Performances[J]. INORGANIC CHEMISTRY,2018,57(9):4820-4823.
APA Zhang, ZZ ,Wang, Y ,Zhang, BB ,Yang, ZH ,&Pan, SL .(2018).CaB5O7F3: A Beryllium-Free Alkaline-Earth Fluorooxoborate Exhibiting Excellent Nonlinear Optical Performances.INORGANIC CHEMISTRY,57(9),4820-4823.
MLA Zhang, ZZ ,et al."CaB5O7F3: A Beryllium-Free Alkaline-Earth Fluorooxoborate Exhibiting Excellent Nonlinear Optical Performances".INORGANIC CHEMISTRY 57.9(2018):4820-4823.
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