Phase behaviours of a cationic surfactant in deep eutectic solvents: from micelles to lyotropic liquid crystals
Li, QT (Li, Qintang); Wang, J (Wang, Jiao); Lei, NN (Lei, Nana); Yan, MH (Yan, Minhao); Chen, X (Chen, Xiao); Yue, X (Yue, Xiu)
2018
发表期刊PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷号20期号:17页码:12175-12181
摘要

In recent years, aggregates formed in deep eutectic solvents (DESs), especially micelles, have attracted much attention. In this study, the phase behaviours of a cationic surfactant, cetylpyridinium bromide (CPBr), in two DESs, choline chloride + glycerol (ChG) and choline chloride + ethylene glycol (ChEG), were investigated in wide concentration and temperature ranges. With the help of small angle X-ray scattering, polarized optical microscopy and rheological measurements, the structures and properties of various aggregates were characterized. The micelles, hexagonal phase, bicontinuous cubic phase and lamellar phase were observed with the increase of CPBr concentration. Such rich phase behaviours were due to the large cohesive energy densities of DESs. Comparative studies in water and ethylammonium nitrate were carried out to explore how well DESs acted as self-assembly media.

DOI10.1039/c8cp00001h
收录类别SCI
WOS记录号WOS:000431824000072
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5406
专题中国科学院特殊环境功能材料与器件重点试验室
作者单位1.Southwest Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Environm Friendly Energy Mat, Mianyang 621000, Peoples R China
2.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China
3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China
4.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
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GB/T 7714
Li, QT ,Wang, J ,Lei, NN ,et al. Phase behaviours of a cationic surfactant in deep eutectic solvents: from micelles to lyotropic liquid crystals[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(17):12175-12181.
APA Li, QT ,Wang, J ,Lei, NN ,Yan, MH ,Chen, X ,&Yue, X .(2018).Phase behaviours of a cationic surfactant in deep eutectic solvents: from micelles to lyotropic liquid crystals.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(17),12175-12181.
MLA Li, QT ,et al."Phase behaviours of a cationic surfactant in deep eutectic solvents: from micelles to lyotropic liquid crystals".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.17(2018):12175-12181.
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