Fabrication and properties of high B value [Mn1.56Co0.96Ni0.48O4](1-x)[SrMnO3](x) (0 <= x <= 0.5) spinel-perovskite composite NTC films
Zhang, J (Zhang, Jun); Kong, WW (Kong, Wenwen); Chang, AM (Chang, Aimin); Kong, WW; Chang, AM
2018
发表期刊JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
卷号29期号:11页码:9613-9620
摘要

The [Mn1.56Co0.96Ni0.48O4](1-x)[SrMnO3](x) ((MCN)(1-x)(SM)(x), 0 <= x <= 0.5) ceramic thin composite films were grown on SiO2/Si (100) substrates by the chemical solution deposition (CSD) method. The results of X-ray diffraction showed that the (MCN)(1-x)(SM)(x) (0 < x <= 0.5) films were a resemblance of the spinel-perovskite composite structure. The field emission scanning electron microscope analyses presented a considerable improvement in relative density with the increasing of the SM contents. In particular, the thermal constant of (MCN)(1-x)(SM)(x) ceramic film increased from 3289 to 5390 K with the increasing of the SM contents (x) from 0 to 0.5. This feature was attributed to the increase in the grain boundary resistance and the increase in Mn3+/Mn4+ pairs as the SM contents increased. From the spectroscopic ellipsometer spectroscopy results, it was found that the (MCN)(0.5)(SM)(0.5) film had the biggest refractive index n value of 2.36 at 1.5 eV and a strong absorption peak at 4.0 eV. The sensitivity of MCN spinel ceramic film was enhanced by the compounding of SM. It was a significant disposition in the study of negative temperature coefficient thermistors.

DOI10.1007/s10854-018-8997-0
收录类别SCI
WOS记录号WOS:000432326800087
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5399
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Kong, WW; Chang, AM
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Zhang, J ,Kong, WW ,Chang, AM ,et al. Fabrication and properties of high B value [Mn1.56Co0.96Ni0.48O4](1-x)[SrMnO3](x) (0 <= x <= 0.5) spinel-perovskite composite NTC films[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,2018,29(11):9613-9620.
APA Zhang, J ,Kong, WW ,Chang, AM ,Kong, WW,&Chang, AM.(2018).Fabrication and properties of high B value [Mn1.56Co0.96Ni0.48O4](1-x)[SrMnO3](x) (0 <= x <= 0.5) spinel-perovskite composite NTC films.JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,29(11),9613-9620.
MLA Zhang, J ,et al."Fabrication and properties of high B value [Mn1.56Co0.96Ni0.48O4](1-x)[SrMnO3](x) (0 <= x <= 0.5) spinel-perovskite composite NTC films".JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS 29.11(2018):9613-9620.
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