0.1%Rh基催化剂上双环戊二烯氢甲酰化
尹铎; 马昱博; 高志贤; 吾满江·艾力
2014
Conference Name中国化学会第29届学术年会
Conference Date2014-08-04
Conference Place中国北京
Abstract

本文以粉体二氧化硅、颗粒二氧化硅,粉体氧化铝,颗粒氧化铝,MCM-41担载的0.1%Rh催化剂对双环戊二烯氢甲酰化合成三环癸烷不饱和单醛进行了对比研究,其中颗粒二氧化硅和粉体氧化铝具有最短的诱导期,仅有3min;以粉体二氧化硅和粉体氧化铝担载的0.1%Rh为催化剂,可取得高达98.5%三环癸烷不饱和单醛的选择性;因此,较合适的高效合成三环癸烷不饱和单醛的载体为粉体二氧化硅和粉体氧化铝.

Keyword双环戊二烯 氢甲酰化 三环癸烷不饱和单醛 载体
Funding Organization中国化学会
Document Type会议论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5353
Collection新疆维吾尔自治区精细化工工程技术研究中心
Affiliation1.中国科学院新疆理化技术研究所精细化工工程中心
2.中国科学院大学
3.中国科学院山西煤炭化学研究所
Recommended Citation
GB/T 7714
尹铎,马昱博,高志贤,等. 0.1%Rh基催化剂上双环戊二烯氢甲酰化[C],2014.
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