Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes
Feng, J (Feng, Jie); Ma, PJ (Ma, Peng-Ju); Zeng, YM (Zeng, Yong-Ming); Xu, YJ (Xu, Yan-Jun); Lu, CD (Lu, Chong-Dao); Lu, CD
2018
发表期刊CHEMICAL COMMUNICATIONS
卷号54期号:23页码:2882-2885
摘要

A dimethyl phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes was developed. Nitrosoarenes were successfully used as electrophiles to trap aza-enolate intermediates that were generated from nucleophilic addition of deprotonated phosphite to alpha-keto N-tert-butanesulfinyl imidates and following phospha-Brook rearrangement, allowing efficient construction of ketonitrones with excellent (Z)-geometries.

DOI10.1039/c8cc00345a
收录类别SCI
WOS记录号WOS:000428844500013
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5271
专题省部共建新疆特有药用资源利用重点实验室
通讯作者Lu, CD
作者单位1.Changji Univ, Dept Chem & Appl Chem, Changji 831100, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China
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GB/T 7714
Feng, J ,Ma, PJ ,Zeng, YM ,et al. Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes[J]. CHEMICAL COMMUNICATIONS,2018,54(23):2882-2885.
APA Feng, J ,Ma, PJ ,Zeng, YM ,Xu, YJ ,Lu, CD ,&Lu, CD.(2018).Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes.CHEMICAL COMMUNICATIONS,54(23),2882-2885.
MLA Feng, J ,et al."Construction of alpha-methoxyimidoyl ketonitrones via phosphite-mediated addition of alpha-keto N-tert-butanesulfinyl imidates to nitrosoarenes".CHEMICAL COMMUNICATIONS 54.23(2018):2882-2885.
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