LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge
Yang, Y (Yang, Yun); Kong, QR (Kong, Qingrong); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2018
发表期刊INORGANIC CHEMISTRY
ISSN0020-1669
卷号57期号:5页码:2876-2882
摘要

hi the Li2O-Na2O-B2O3 system, LiNa4B15O25 has been successfully synthesized, which crystallizes in monoclinic space group C2/c (No. 15), a = 14.153(3) angstrom, b = 12.122(2) angstrom, c 12.719(2) angstrom, beta = 105.237(13)degrees, and Z = 4. The isolated LiO5 polyhedra and the Na4O15 tetramers are located in the void space of the 3D (infinity)[B15O25] network of LiNa4B15O25. The symmetry of B15O30 is a new fundamental building block, which has never been reported before. Moreover, the whole framework can be defined as a new topology based on the TOPOS database. Interestingly, for the crystal structure LiB3O5, as 4/5 Li+ ions are substituted by the Na+ ions, a new compound LiNa4B15O25 has been successfully prepared. The structural comparison between the structures of LiB3O5 and LiNa4B15O25 and the changes caused by the cation substitution are discussed in this paper.

DOI10.1021/acs.inorgchem.7b03243
收录类别SCI
WOS记录号WOS:000427094000062
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5261
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Pan, SL (Pan, Shilie)
作者单位1.CAS Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
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GB/T 7714
Yang, Y ,Kong, QR ,Yang, ZH ,et al. LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge[J]. INORGANIC CHEMISTRY,2018,57(5):2876-2882.
APA Yang, Y ,Kong, QR ,Yang, ZH ,&Pan, SL .(2018).LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge.INORGANIC CHEMISTRY,57(5),2876-2882.
MLA Yang, Y ,et al."LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge".INORGANIC CHEMISTRY 57.5(2018):2876-2882.
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