A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+
Wang, Z (Wang, Zheng); Jing, Q (Jing, Qun); Zhang, M (Zhang, Min); Dong, XY (Dong, Xiaoyu); Pan, SL (Pan, Shilie); Yang, ZH (Yang, Zhihua)
2014
Source PublicationRSC ADVANCES
ISSN2046-2069
Volume4Issue:97Pages:54194-54198
Abstract

A new 12L-hexagonal perovskite Cs4Mg3CaF12 was synthesized using an open high-temperature solution method. It crystallizes in the trigonal space group R3m (no. 166) with lattice constants a = 6.2196(9) angstrom, c = 29.812(9) angstrom, Z = 3. Cs4Mg3CaF12 is changed from the cubic phase CsMgF3 by replacing 25% Mg2+ with Ca2+. The changes derived from the substitution and the structural comparison between Cs4Mg3CaF12 and other perovskites are discussed in this paper. Thermal analysis, infrared spectroscopy, and electronic structure calculations were performed on the reported material.

DOI10.1039/c4ra07819e
Indexed BySCI
WOS IDWOS:000344600400008
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Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5231
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, M (Zhang, Min)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Z ,Jing, Q ,Zhang, M ,et al. A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+[J]. RSC ADVANCES,2014,4(97):54194-54198.
APA Wang, Z ,Jing, Q ,Zhang, M ,Dong, XY ,Pan, SL ,&Yang, ZH .(2014).A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+.RSC ADVANCES,4(97),54194-54198.
MLA Wang, Z ,et al."A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+".RSC ADVANCES 4.97(2014):54194-54198.
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