A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+
Wang, Z (Wang, Zheng); Jing, Q (Jing, Qun); Zhang, M (Zhang, Min); Dong, XY (Dong, Xiaoyu); Pan, SL (Pan, Shilie); Yang, ZH (Yang, Zhihua)
2014
发表期刊RSC ADVANCES
ISSN2046-2069
卷号4期号:97页码:54194-54198
摘要

A new 12L-hexagonal perovskite Cs4Mg3CaF12 was synthesized using an open high-temperature solution method. It crystallizes in the trigonal space group R3m (no. 166) with lattice constants a = 6.2196(9) angstrom, c = 29.812(9) angstrom, Z = 3. Cs4Mg3CaF12 is changed from the cubic phase CsMgF3 by replacing 25% Mg2+ with Ca2+. The changes derived from the substitution and the structural comparison between Cs4Mg3CaF12 and other perovskites are discussed in this paper. Thermal analysis, infrared spectroscopy, and electronic structure calculations were performed on the reported material.

DOI10.1039/c4ra07819e
收录类别SCI
WOS记录号WOS:000344600400008
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5231
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Zhang, M (Zhang, Min)
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Wang, Z ,Jing, Q ,Zhang, M ,et al. A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+[J]. RSC ADVANCES,2014,4(97):54194-54198.
APA Wang, Z ,Jing, Q ,Zhang, M ,Dong, XY ,Pan, SL ,&Yang, ZH .(2014).A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+.RSC ADVANCES,4(97),54194-54198.
MLA Wang, Z ,et al."A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+".RSC ADVANCES 4.97(2014):54194-54198.
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