Optochemical properties of gas-phase protonated tetraphenylporphyrin investigated using an optical waveguide NH3 sensor
Tuerdi, G (Tuerdi, Gulimire); Nizamidin, P (Nizamidin, Patima); Kari, N (Kari, Nuerguli); Yimit, A (Yimit, Abliz); Wang, F (Wang, Fu)
2018
发表期刊RSC ADVANCES
ISSN2046-2069
卷号8期号:10页码:5614-5621
摘要

5,10,15,20-Tetraphenylporphyrin (TPP) was synthesized, and a glass optical waveguide (OWG, which restricts and maintains the light energy in a specific, narrow space and propagates along the space axially) was coated with a gas-phase protonated TPP thin film to develop a sensor for NH3 gas detection. The results show that the TPP thin film agglomerated into H-based J-type aggregates after H2S gas exposure. The molecules in the protonated TPP film OWG sensor acted as NH3 receptors because the gas-phase protonated TPP film morphologically changed from J-type aggregates into free-base monomers when it was deprotonated by NH3 exposure. In this case, H2S gas could be used to increase the relative amount of J-type aggregates in the TPP film and restore the sensor response. The reversible surface morphology of the TPP film was analyzed by H-1 NMR spectroscopy, atomic force microscopy, and UV-vis spectroscopy.

DOI10.1039/c7ra11643h
收录类别SCI
WOS记录号WOS:000424024200062
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5213
专题中国科学院特殊环境功能材料与器件重点试验室
作者单位1.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Lab Environm Sci & Technol, Urumqi 830011, Peoples R China
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Tuerdi, G ,Nizamidin, P ,Kari, N ,et al. Optochemical properties of gas-phase protonated tetraphenylporphyrin investigated using an optical waveguide NH3 sensor[J]. RSC ADVANCES,2018,8(10):5614-5621.
APA Tuerdi, G ,Nizamidin, P ,Kari, N ,Yimit, A ,&Wang, F .(2018).Optochemical properties of gas-phase protonated tetraphenylporphyrin investigated using an optical waveguide NH3 sensor.RSC ADVANCES,8(10),5614-5621.
MLA Tuerdi, G ,et al."Optochemical properties of gas-phase protonated tetraphenylporphyrin investigated using an optical waveguide NH3 sensor".RSC ADVANCES 8.10(2018):5614-5621.
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