An unusual density evolution between SrCdB2O5 polymorphs
Zhang, XW (Zhang, Xingwen); Zhou, ZY (Zhou, Zhengyang); Wu, HP (Wu, Hongping); Pan, SL (Pan, Shilie); Lei, C (Lei, Chen); Liu, L (Liu, Lu); Yang, ZH (Yang, Zhihua)
2015
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume44Issue:36Pages:15823-15828
Abstract

Owing to the effect of atomic vibrations, a high-temperature phase usually features a relatively smaller density when compared with a low-temperature phase. In this work, a new SrCdB2O5 phase has been discovered. According to the crystallization temperature from low to high, the new SrCdB2O5 phase can be regarded as the high-temperature beta-SrCdB2O5 phase. The density of beta-SrCdB2O5 is obviously larger than that of alpha-SrCdB2O5, meanwhile beta-SrCdB2O5 is energetically favored. This unusual density evolution phenomenon has been investigated. In addition, the Pb2+-doped compounds, PbxSr1-xCdB2O5 (x = 0.125, 0.25, 0.375, 0.5), have also been investigated by powder refinement.

DOI10.1039/c5dt00915d
Indexed BySCI
WOS IDWOS:000360471000011
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5183
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Zhang, XW ,Zhou, ZY ,Wu, HP ,et al. An unusual density evolution between SrCdB2O5 polymorphs[J]. DALTON TRANSACTIONS,2015,44(36):15823-15828.
APA Zhang, XW .,Zhou, ZY .,Wu, HP .,Pan, SL .,Lei, C .,...&Yang, ZH .(2015).An unusual density evolution between SrCdB2O5 polymorphs.DALTON TRANSACTIONS,44(36),15823-15828.
MLA Zhang, XW ,et al."An unusual density evolution between SrCdB2O5 polymorphs".DALTON TRANSACTIONS 44.36(2015):15823-15828.
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