Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O
Zhang, FY (Zhang, Fangyuan); Zhang, FF (Zhang, Fangfang); Qun, J (Qun, Jing); Pan, SL (Pan, Shilie); Yang, ZH (Yang, Zhihua); Jia, DZ (Jia, Dianzeng)
2015
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN1463-9076
Volume17Issue:16Pages:10489-10496
Abstract

Strontium borate Sr2B5O9(OH)center dot H2O (space group C2, No. 5) has been synthesized in high yields using a facile hydrothermal method. The UV-Vis-NIR diffuse reflectance spectrum shows that it has a wide transparency range extending from UV to NIR with the short-wavelength cut off edge below 190 nm. Second-harmonic generation (SHG) has been measured with a 1064 nm laser using the Kurtz and Perry technique, which shows that Sr2B5O9(OH)center dot H2O is phase matchable and the powder SHG effect is approximately 3 times that of KDP. It also has a high thermal stability up to 500 degrees C which has been identified by TG, DSC and variable-temperature PXRD. These properties make it possible for application as a UV nonlinear optical (NLO) material. Based on the electronic band structure, the optical refractive indices, birefringence, and SHG coefficients of Sr2B5O9(OH)center dot H2O are calculated, which are consistent with experiments. In addition, the electronic structure, SHG-weighted electron density and real-space atom-cutting analyses are performed to elucidate the origin of its NLO properties.

DOI10.1039/c5cp00864f
Indexed BySCI
WOS IDWOS:000352707200021
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5171
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, FF (Zhang, Fangfang)
Affiliation1.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Zhang, FY ,Zhang, FF ,Qun, J ,et al. Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2015,17(16):10489-10496.
APA Zhang, FY ,Zhang, FF ,Qun, J ,Pan, SL ,Yang, ZH ,&Jia, DZ .(2015).Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,17(16),10489-10496.
MLA Zhang, FY ,et al."Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)center dot H2O".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 17.16(2015):10489-10496.
Files in This Item:
File Name/Size DocType Version Access License
Synthesis, character(2449KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, FY (Zhang, Fangyuan)]'s Articles
[Zhang, FF (Zhang, Fangfang)]'s Articles
[Qun, J (Qun, Jing)]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, FY (Zhang, Fangyuan)]'s Articles
[Zhang, FF (Zhang, Fangfang)]'s Articles
[Qun, J (Qun, Jing)]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, FY (Zhang, Fangyuan)]'s Articles
[Zhang, FF (Zhang, Fangfang)]'s Articles
[Qun, J (Qun, Jing)]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Synthesis, characterization and theoretical studies of nonlinear optical crystal Sr2B5O9(OH)·H2O.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.