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Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant
Wusiman, A (Wusiman, Abudureheman); Lu, CD (Lu, Chong-Dao)
2015
发表期刊APPLIED ORGANOMETALLIC CHEMISTRY
卷号29期号:4页码:254-258
摘要

We show that the dirhodium(II) tetraamidinate complex Rh-2(Msip)(4) efficiently catalyzes the oxidation of activated secondary alcohols at only 0.1 mol% loading. In this approach, we oxidized various benzylic, allylic and propargylic alcohols to the corresponding carbonyl compounds under mild aqueous conditions using the inexpensive oxidant T-HYDRO (R) (70 wt% aqueous tert-butyl hydroperoxide).

关键词Dirhodium(Ii) Catalyst Oxidation Alcohols Tert-butyl Hydroperoxide
DOI10.1002/aoc.3281
收录类别SCI
WOS记录号WOS:000351603700013
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5167
专题资源化学研究室
作者单位1.Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
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Wusiman, A ,Lu, CD . Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant[J]. APPLIED ORGANOMETALLIC CHEMISTRY,2015,29(4):254-258.
APA Wusiman, A ,&Lu, CD .(2015).Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant.APPLIED ORGANOMETALLIC CHEMISTRY,29(4),254-258.
MLA Wusiman, A ,et al."Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant".APPLIED ORGANOMETALLIC CHEMISTRY 29.4(2015):254-258.
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