Pb7O(OH)(3)(CO3)(3)(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response
Abudoureheman, M (Abudoureheman, Maierhaba); Wang, L (Wang, Li); Zhang, XM (Zhang, Xianming); Yu, HW (Yu, Hongwei); Yang, ZH (Yang, Zhihua); Lei, C (Lei, Chen); Han, J (Han, Jian); Pan, SL (Pan, Shilie)
2015
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume54Issue:8Pages:4138-4142
Abstract

The first borate carbonate UV nonlinear optical material Pb7O(OH)(3)(CO3)(3)(BO3) was hydrothermally synthesized, which features a (3,9)-connected IrSi3-like structure constructed by Pb7O(OH)(3)(BO3) units and carbonates. This compound exhibits a large second-harmonic generation (SHG) response about 4.5 times that of KH2PO4 (KDP), attributed to synergistic interactions between the stereoeffect of the Pb(II) cations and coparallel BO3 and CO3 triangles groups.

DOI10.1021/acs.inorgchem.5b00401
Indexed BySCI
WOS IDWOS:000353429500050
Citation statistics
Cited Times:36[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5163
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Affiliation1.Xinjiang Normal Univ, Coll Chem & Chem Engn, Urumqi 830054, Peoples R China
2.Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Peoples R China
3.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Abudoureheman, M ,Wang, L ,Zhang, XM ,et al. Pb7O(OH)(3)(CO3)(3)(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response[J]. INORGANIC CHEMISTRY,2015,54(8):4138-4142.
APA Abudoureheman, M .,Wang, L .,Zhang, XM .,Yu, HW .,Yang, ZH .,...&Pan, SL .(2015).Pb7O(OH)(3)(CO3)(3)(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response.INORGANIC CHEMISTRY,54(8),4138-4142.
MLA Abudoureheman, M ,et al."Pb7O(OH)(3)(CO3)(3)(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response".INORGANIC CHEMISTRY 54.8(2015):4138-4142.
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