Polar Polymorphism: alpha-, beta-, and gamma-Pb2Ba4Zn4B14O31 Synthesis, Characterization, and Nonlinear Optical Properties
Yu, HW (Yu, Hongwei); Wu, HP (Wu, Hongping); Jing, Q (Jing, Qun); Yang, ZH (Yang, Zhihua); Haasyamani, PS (Haasyamani, P. Shiv); Pan, SL (Pan, Shilie)
2015
发表期刊CHEMISTRY OF MATERIALS
ISSN0897-4756
卷号27期号:13页码:4779-4788
摘要

Polar materials are critical for a variety of functional properties including ferroelectricity, pyroelectricity, and nonlinear optical behavior. Vital to developing new polar materials is an understanding of how the polarity influences the functional property, i.e., structure property relationships. At present, structure property relationships on polar materials have focused on materials with similar structural motifs. Interestingly, there are limited reports on the structure property relationships of polar polymorphs, likely attributable to the challenge of synthesizing polar polymorphic materials. In this paper, a new strategy for the synthesis of polar polymorphs is presented. By employing this strategy, we report on the synthesis and characterization of the first example of a borate with all polar polymorphs: PI for alpha-Pb2Ba4Zn4B14O31 (alpha-PBZB), Cc for,beta-PBZB, and P3(2) for gamma-PBZB. In addition, powder second-harmonic generation (PSHG) measurements indicate that the polymorphs are SHG-active and type-I phase matchable. Structure-property relationships are discussed through theoretical calculations.

DOI10.1021/acs.chemmater.5b01579
收录类别SCI
WOS记录号WOS:000358104700033
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5151
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China
2.Univ Houston, Dept Chem, Houston, TX 77204 USA
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Yu, HW ,Wu, HP ,Jing, Q ,et al. Polar Polymorphism: alpha-, beta-, and gamma-Pb2Ba4Zn4B14O31 Synthesis, Characterization, and Nonlinear Optical Properties[J]. CHEMISTRY OF MATERIALS,2015,27(13):4779-4788.
APA Yu, HW ,Wu, HP ,Jing, Q ,Yang, ZH ,Haasyamani, PS ,&Pan, SL .(2015).Polar Polymorphism: alpha-, beta-, and gamma-Pb2Ba4Zn4B14O31 Synthesis, Characterization, and Nonlinear Optical Properties.CHEMISTRY OF MATERIALS,27(13),4779-4788.
MLA Yu, HW ,et al."Polar Polymorphism: alpha-, beta-, and gamma-Pb2Ba4Zn4B14O31 Synthesis, Characterization, and Nonlinear Optical Properties".CHEMISTRY OF MATERIALS 27.13(2015):4779-4788.
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