Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials
Mutailipu, M (Mutailipu, Miriding); Xie, ZQ (Xie, Zhiqing); Su, X (Su, Xin); Zhang, M (Zhang, Min); Wang, Y (Wang, Ying); Yang, ZH (Yang, Zhihua); Janjua, MRSA (Janjua, Muhammad Ramzan Saeed Ashraf); Pan, SL (Pan, Shilie)
2017
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume139Issue:50Pages:18397-18405
Abstract

A chemical cosubstitution strategy was implemented to design potential ultraviolet (UV) and deep-UV nonlinear optical (NLO) materials. Taking the classic beta-BaB2O4 as a maternal structure, by simultaneously replacing the Ba2+ and [B3O6](3- )units with monovalant (K+), divalent (alkaline earth metal), trivalent (rare-earth metal, Bi3+) ions, and the [B5O10](5- )clusters through two different practical routes, 12 new mixed-metal noncentrosymmetric borates (K7MRE2)-R-II(B5O10)(3) (M-II = Ca, Sr, Ba, K/RE0.5; RE = Y, Lu, Gd) as well as (K7MBi2)-Bi-II(B5O10)(3) (M-II = Pb, Sr) were successfully designed and synthesized as high-quality single crystals. The selected K7CaY2(B5O10)(3), K7SrY2(B5O10)(3), and K7BaY2(B5O10)(3 )compounds were subjected to experimental and theoretical characterizations. They all exhibit suitable second-harmonic generation (SHG) responses, as large as that of commercial KH2PO4 (KDP), and also exhibit short UV cutoff edges. These results confirm the feasibility of this chemical cosubstitution strategy to design NLO materials and that the three selected crystals may have potential application as UV NLO materials.

DOI10.1021/jacs.7b11263
Indexed BySCI
WOS IDWOS:000418783600042
Citation statistics
Cited Times:41[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5118
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, M (Zhang, Min); Wang, Y (Wang, Ying); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condensed, Yining 835000, Xinjiang, Peoples R China
5.King Fahd Univ Petr & Minerals, Chem Dept, Dhahran 31261, Saudi Arabia
Recommended Citation
GB/T 7714
Mutailipu, M ,Xie, ZQ ,Su, X ,et al. Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(50):18397-18405.
APA Mutailipu, M .,Xie, ZQ .,Su, X .,Zhang, M .,Wang, Y .,...&Pan, SL .(2017).Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(50),18397-18405.
MLA Mutailipu, M ,et al."Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.50(2017):18397-18405.
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