Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials
Mutailipu, M (Mutailipu, Miriding); Xie, ZQ (Xie, Zhiqing); Su, X (Su, Xin); Zhang, M (Zhang, Min); Wang, Y (Wang, Ying); Yang, ZH (Yang, Zhihua); Janjua, MRSA (Janjua, Muhammad Ramzan Saeed Ashraf); Pan, SL (Pan, Shilie); Zhang, M; Wang, Y; Pan, SL
2017
发表期刊JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷号139期号:50页码:18397-18405
摘要

A chemical cosubstitution strategy was implemented to design potential ultraviolet (UV) and deep-UV nonlinear optical (NLO) materials. Taking the classic beta-BaB2O4 as a maternal structure, by simultaneously replacing the Ba2+ and [B3O6](3- )units with monovalant (K+), divalent (alkaline earth metal), trivalent (rare-earth metal, Bi3+) ions, and the [B5O10](5- )clusters through two different practical routes, 12 new mixed-metal noncentrosymmetric borates (K7MRE2)-R-II(B5O10)(3) (M-II = Ca, Sr, Ba, K/RE0.5; RE = Y, Lu, Gd) as well as (K7MBi2)-Bi-II(B5O10)(3) (M-II = Pb, Sr) were successfully designed and synthesized as high-quality single crystals. The selected K7CaY2(B5O10)(3), K7SrY2(B5O10)(3), and K7BaY2(B5O10)(3 )compounds were subjected to experimental and theoretical characterizations. They all exhibit suitable second-harmonic generation (SHG) responses, as large as that of commercial KH2PO4 (KDP), and also exhibit short UV cutoff edges. These results confirm the feasibility of this chemical cosubstitution strategy to design NLO materials and that the three selected crystals may have potential application as UV NLO materials.

DOI10.1021/jacs.7b11263
收录类别SCI
WOS记录号WOS:000418783600042
引用统计
被引频次:16[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5118
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Zhang, M; Wang, Y; Pan, SL
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condensed, Yining 835000, Xinjiang, Peoples R China
5.King Fahd Univ Petr & Minerals, Chem Dept, Dhahran 31261, Saudi Arabia
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Mutailipu, M ,Xie, ZQ ,Su, X ,et al. Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(50):18397-18405.
APA Mutailipu, M .,Xie, ZQ .,Su, X .,Zhang, M .,Wang, Y .,...&Pan, SL.(2017).Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(50),18397-18405.
MLA Mutailipu, M ,et al."Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.50(2017):18397-18405.
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