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Kinetics of dicyclopentadiene hydroformylation over Rh-SiO2 catalysts
Ma, YB (Ma, Yubo); Gao, ZX (Gao, Zhixian); Yuan, T (Yuan, Tao); Wang, TF (Wang, Tianfu)
2017
Source PublicationPROGRESS IN REACTION KINETICS AND MECHANISM
ISSN1468-6783
Volume42Issue:2Pages:191-199
Abstract

The hydroformylation of dicyclopentadiene (DCPD) to monoformyltricyclodecenes (MFTD) represents a key intermediate step in the conversion of the C5 fraction derived from the petrochemical process to value-added fine chemicals, for example, diformyltricyclodecanes and tricyclodecanedimethylol. Although both heterogeneous and homogeneous catalysts can catalyse this reaction, the heterogeneously catalysed pathway has received significantly less attention due to its lower catalytic activities. We demonstrate in this work that a low Rh loaded heterogeneous 0.1% Rh-SiO2 catalyst can present a similar performance relative to the homogeneous Rh(PPh3)Cl, a reference catalyst for this reaction. Furthermore, an extensive kinetic study of DCPD hydroformylation to MFTD using heterogeneous 0.1% Rh-SiO2 catalysts has been performed. A series of kinetic experiments was carried out over a broad range of conditions (temperature: 100-120 degrees C; pressure: 1.5-5 MPa; catalyst-to-reactant mass ratio: 0.02-0.05; PPh3 concentration: 5-12.5 g L-1). A kinetic analysis was carried out, indicating the activation energy for the reaction to be 84.7 Id mol(-1). DCPD conversion and MFTD yield could be optimised to be as high as 99% at 0.1% Rh loading, a DCPD/catalyst mass ratio of 25, a PPh3 concentration of 10 g L-1, a reaction time of 4 h and a reaction pressure of 4 MPa.

KeywordDicyclopentadiene Monoformyltricyclodecenes Kinetics 0.1% Rh-sio2
DOI10.3184/146867817X14821527549013
Indexed BySCI
WOS IDWOS:000404830000009
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5099
Collection资源化学研究室
Corresponding AuthorWang, TF (Wang, Tianfu)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Inst Coal Chem, Taiyuan 030001, Peoples R China
Recommended Citation
GB/T 7714
Ma, YB ,Gao, ZX ,Yuan, T ,et al. Kinetics of dicyclopentadiene hydroformylation over Rh-SiO2 catalysts[J]. PROGRESS IN REACTION KINETICS AND MECHANISM,2017,42(2):191-199.
APA Ma, YB ,Gao, ZX ,Yuan, T ,&Wang, TF .(2017).Kinetics of dicyclopentadiene hydroformylation over Rh-SiO2 catalysts.PROGRESS IN REACTION KINETICS AND MECHANISM,42(2),191-199.
MLA Ma, YB ,et al."Kinetics of dicyclopentadiene hydroformylation over Rh-SiO2 catalysts".PROGRESS IN REACTION KINETICS AND MECHANISM 42.2(2017):191-199.
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