Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77
Abudoureheman, M (Abudoureheman, Maierhaba); Han, SJ (Han, Shujuan); Wang, Y (Wang, Ying); Liu, Q (Liu, Qiong); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2017
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume56Issue:21Pages:13456-13463
Abstract

Three new mixed-alkaline borates Na2M2B20O33 (M = Rb, Cs) and Li4Cs4B40O64 with unique structures were synthesized by the spontaneous nucleation method, and their structures were determined by single-crystal X-ray diffraction. The B-O networks of Na2M2B20O32 (M = Rb, Cs) are constructed by two independent interpenetrating three-dimensional (3D) frameworks, which is the first case in anhydrous mixed-alkaline borate systems. In addition, Li4Cs4B40O64 shows high B-O polymerization with a new fundamental building block B40O77. Meanwhile, detailed structure comparisons containing the cation effect on the framework have been discussed. UV-vis-NIR diffuse reflectance spectra and the infrared spectra were measured. The band structures and the density of states were performed using, density functional theory calculation.

DOI10.1021/acs.inorgchem.7602168
Indexed BySCI
WOS IDWOS:000414820100086
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5080
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorHan, SJ (Han, Shujuan); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Abudoureheman, M ,Han, SJ ,Wang, Y ,et al. Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77[J]. INORGANIC CHEMISTRY,2017,56(21):13456-13463.
APA Abudoureheman, M ,Han, SJ ,Wang, Y ,Liu, Q ,Yang, ZH ,&Pan, SL .(2017).Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77.INORGANIC CHEMISTRY,56(21),13456-13463.
MLA Abudoureheman, M ,et al."Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77".INORGANIC CHEMISTRY 56.21(2017):13456-13463.
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