ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges
Ma, RR (Ma, Ruru); Xu, DD (Xu, Dongdong); Yang, Y (Yang, Yun); Su, X (Su, Xin); Lei, BH (Lei, Binghua); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2017
Source PublicationDALTON TRANSACTIONS
ISSN1477-9226
Volume46Issue:43Pages:14839-14846
Abstract

Two new isostructural rare-earth oxyborates ScMO(BO3) (M = Ca and Cd) with a three-dimensional (3D) cationic framework and parallel arranged [BO3] triangles have been synthesized by the flux method. In the 3D cationic framework, an interesting sandwich-like basic building unit (BBU) is constructed by two 1(infinity)[Ca(1) O-4](6-) chains and two 1(infinity)[Sc(1) O-4](5-) chains. ScMO(BO3) melt incongruently, which shows that title compounds can be grown by the flux method. The UV cut-off edges for ScCaO(BO3) and ScCdO(BO3) are 230 and 249 nm, respectively. In addition, the first-principles calculations are performed to gain further insights into the relationship between the microscopic electronic structures and associated optical properties

DOI10.1039/c7dt03172f
Indexed BySCI
WOS IDWOS:000414775000019
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5078
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorYang, Y (Yang, Yun); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ma, RR ,Xu, DD ,Yang, Y ,et al. ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges[J]. DALTON TRANSACTIONS,2017,46(43):14839-14846.
APA Ma, RR .,Xu, DD .,Yang, Y .,Su, X .,Lei, BH .,...&Pan, SL .(2017).ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges.DALTON TRANSACTIONS,46(43),14839-14846.
MLA Ma, RR ,et al."ScMO(BO3) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges".DALTON TRANSACTIONS 46.43(2017):14839-14846.
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