New high temperature NTC thermistors based on the Mg(Al1-xCrx)(2)O-4 ceramics
Yang, T (Yang, Tian); Zhang, B (Zhang, Bo); Zhao, Q (Zhao, Qing); Luo, P (Luo, Ping); Chang, AM (Chang, Aimin)
2016
发表期刊JOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
卷号685期号:11页码:287-293
摘要

The new high temperature negative temperature coefficient (NTC) ceramics based on the Mg(Al1-xCrx)(2)O-4 compositions have been investigated. The ceramics were synthesized by conventional solid state reaction at 1650 degrees C. For 0 <= x <= 0.5, the X-ray diffraction analysis has revealed that the sintered ceramics crystallize in a cubic spinel structure. X-ray photoelectron spectroscopy analysis confirms the existence of Cr3+ and Cr4+ ions on lattice sites, which result in hopping conduction. The resistivity decreases with increasing the Cr content. The obtained values of rho(500) and B-500/800 and E-a are in the range of 2.67 x 10(3) -3.72 x 10(7) Omega cm, 6731-11886 K, 0.581-1.025 eV, respectively. The electrical properties of these ceramics can be adjusted by the Cr content. Such ceramics could be suitable for high temperature NTC thermistor application.

关键词Electrical Properties X-ray Photoelectron Spectroscopy Ntc Thermistors Spinel
DOI10.1016/j.jallcom.2016.05.301
收录类别SCI
WOS记录号WOS:000382222300041
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5074
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Zhang, B (Zhang, Bo); Chang, AM (Chang, Aimin)
作者单位1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Xinjiang Univ, Sch Phys Sci & Technol, Urumqi 830046, Peoples R China
推荐引用方式
GB/T 7714
Yang, T ,Zhang, B ,Zhao, Q ,et al. New high temperature NTC thermistors based on the Mg(Al1-xCrx)(2)O-4 ceramics[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2016,685(11):287-293.
APA Yang, T ,Zhang, B ,Zhao, Q ,Luo, P ,&Chang, AM .(2016).New high temperature NTC thermistors based on the Mg(Al1-xCrx)(2)O-4 ceramics.JOURNAL OF ALLOYS AND COMPOUNDS,685(11),287-293.
MLA Yang, T ,et al."New high temperature NTC thermistors based on the Mg(Al1-xCrx)(2)O-4 ceramics".JOURNAL OF ALLOYS AND COMPOUNDS 685.11(2016):287-293.
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