Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2
Wu, HP (Wu, Hongping); Yu, HW (Yu, Hongwei); Pan, SL (Pan, Shilie); Halasyamani, PS (Halasyamani, P. Shiv)
2017
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume56Issue:15Pages:8755-8758
Abstract

A beryllium-free deep-ultraviolet (DUV) nonlinear-optical (NLO) material, K3Sr3Al4Li2B6O20F, has been synthesized and characterized. Unlike KBe2BO3F2 (KBBF), the reported NLO material does not require the use of toxic BeO in the synthesis, and through the judicious selection of cations, strong interlayer interactions are observed that facilitate the crystal growth. K3Sr3Al4Li2B6O20F exhibits second-harmonic generation (SHG) at both 1064 and 532 nm with efficiencies of 1.7KH(2)PO(4) and 0.3 beta-BaB2O4 and has an absorption edge of 190 nm. Because of the strong interlayer interactions, we were able to grow well-faceted large crystals, 8 X 8 X 5 mm(3), through a top-seeded-solution-growth technique. With these crystals, we determined a birefringence of 0.0574 at 1064 nm and a type I phase-matching SHG limit of 224 nm.

DOI10.1021/acs.inorgchem.7b01517
Indexed BySCI
WOS IDWOS:000407405500022
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5045
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Houston, Dept Chem, 112 Fleming Bldg, Houston, TX 77204 USA
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Wu, HP ,Yu, HW ,Pan, SL ,et al. Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2[J]. INORGANIC CHEMISTRY,2017,56(15):8755-8758.
APA Wu, HP ,Yu, HW ,Pan, SL ,&Halasyamani, PS .(2017).Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2.INORGANIC CHEMISTRY,56(15),8755-8758.
MLA Wu, HP ,et al."Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2".INORGANIC CHEMISTRY 56.15(2017):8755-8758.
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