New Compressed Chalcopyrite-like Li(2)BaM(IV)Q(4) (M-IV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials
Wu, K (Wu, Kui); Zhang, BB (Zhang, Bingbing); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2017
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume139Issue:42Pages:14885-14888
Abstract

Chalcopyrite-type AgGaQ(2) (Q = S, Se) and ZnGeP2 are the main commercial infrared nonlinear optical (IR NLO) crystals. Unfortunately, performance defects including low laser damage threshold (LDT), harmful two-photon absorption (TPA), or small birefringence limit their application. With this background, four new compressed chalcopyrite-like IR NLO materials Li(2)BaM(IV)Q(4) (M-IV = Ge, Sn; Q= S, Se) were successfully synthesized with the typical AgGaQ2 as templates. Remarkably, Li2BaGeS4 and Li2BaSnS4 not only maintain the good NLO responses (0.5 and 0.7 X AgGaS2) but also overcome low LDTs and TPA of commercial chalcopyrites, demonstrating that they satisfy critical demands as promising IR NLO candidates. All of them exhibit phase matching abilities. Furthermore, the discovery of chalcopyrite-like compounds also provides a feasible design strategy to explore new promising IR NLO materials.

DOI10.1021/jacs.7b08966
Indexed BySCI
WOS IDWOS:000414115800017
Citation statistics
Cited Times:42[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/5029
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorYang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Wu, K ,Zhang, BB ,Yang, ZH ,et al. New Compressed Chalcopyrite-like Li(2)BaM(IV)Q(4) (M-IV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(42):14885-14888.
APA Wu, K ,Zhang, BB ,Yang, ZH ,&Pan, SL .(2017).New Compressed Chalcopyrite-like Li(2)BaM(IV)Q(4) (M-IV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(42),14885-14888.
MLA Wu, K ,et al."New Compressed Chalcopyrite-like Li(2)BaM(IV)Q(4) (M-IV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.42(2017):14885-14888.
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