CsB4O6F: ACongruent-Melting Deep-Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units
Wang, XF (Wang, Xuefei);   Wang, Y (Wang, Ying);   Zhang, BB (Zhang, Bingbing);   Zhang, FF (Zhang, Fangfang);   Yang, ZH (Yang, Zhihua);   Pan, SL (Pan, Shilie); Wang, Y; Zhang, FF; Pan, SL
2017
发表期刊ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷号56期号:45页码:14119-14123
摘要

The discovery of new nonlinear optical (NLO) materials for coherent light generation in the deep-ultraviolet (DUV, wavelength below 200 nm) region is essential for the development of laser technologies. Herein, we report a new material CsB4O6F (CBF), which combines the superior structural properties of two well-known NLO materials, beta-BaB2O4 (BBO) and KBe2BO3F2 (KBBF). CBF exhibits excellent DUV optical properties including a short cutoff edge (155 nm), a large SHG response (approximate to 1.9 X KDP), and a suitable birefringence that enables frequency doubling down to 171.6 nm. Remarkably, CBF melts congruently and shows an improved growth habit. In addition, our rational design strategy will contribute to the discovery of DUV NLO materials.

关键词Deep-ultraviolet Fluorooxoborates Nonlinear Optical Materials Second Harmonic Generation
DOI10.1002/ange.201708231
收录类别SCI
WOS记录号WOS:000413896400036
引用统计
被引频次:60[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/5023
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Wang, Y; Zhang, FF; Pan, SL
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Wang, XF ,Wang, Y,Zhang, FF,et al. CsB4O6F: ACongruent-Melting Deep-Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(45):14119-14123.
APA Wang, XF ,Wang, Y,Zhang, FF,&Pan, SL.(2017).CsB4O6F: ACongruent-Melting Deep-Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(45),14119-14123.
MLA Wang, XF ,et al."CsB4O6F: ACongruent-Melting Deep-Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.45(2017):14119-14123.
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