Molecularly imprinted polymers prepared using a porogenic solvent of an ionic liquid and a macromolecular crowding agent and their application in purification of oleanic acid
Zhang, C (Zhang, Chen)1; Li, F (Li, Fang)1; Wang, SX (Wang, Si-Xi)1; Liu, ZS (Liu, Zhao-Sheng)1; Aisa, HA (Aisa, Haji Akber)1
2015
发表期刊ANALYTICAL METHODS
卷号7期号:24页码:10256-10265
摘要A strategy to increase the affinity of molecularly imprinted polymers (MIPs) using a novel porogenic solvent was described based on the cooperative effect of ionic liquids and macromolecular crowding agents. A typical porogenic solvent is composed of a ternary mixture of polymethylmethacrylate (PMAA) solution in chloroform, dimethyl sulfoxide and 1-butyl-3-methylimidazolium tetrafluoroborate. The method can produce 4-vinylpyridine-based MIP monoliths with good permeability. The influence of some important polymerization variables, i.e., PMMA concentration, the type of ionic liquid and crowding agent, and the ratio between PMMA and the ionic liquid, on the imprinting performance was studied. The cooperative effect of the macromolecular crowding agent and ionic liquid was demonstrated by comparing the imprinting effect of the MIPs with other polymers made with only the macromolecular crowding agent or ionic liquid. The type of macromolecular crowding agent and ionic liquid has significantly influenced the imprinting performance of the achieved MIPs. The resulting oleanic acid (OA) MIP can be used to purify OA from the crude extract efficiently with a mean recovery of 72.32%.
DOI10.1039/c5ay01960e
WOS记录号WOS:000365912900023
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被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4995
专题省部共建新疆特有药用资源利用重点实验室
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, State Key Lab Basis Xinjiang Indigenous Med Plant, Xinjiang 830011, Peoples R China
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Zhang, C ,Li, F ,Wang, SX ,et al. Molecularly imprinted polymers prepared using a porogenic solvent of an ionic liquid and a macromolecular crowding agent and their application in purification of oleanic acid[J]. ANALYTICAL METHODS,2015,7(24):10256-10265.
APA Zhang, C ,Li, F ,Wang, SX ,Liu, ZS ,&Aisa, HA .(2015).Molecularly imprinted polymers prepared using a porogenic solvent of an ionic liquid and a macromolecular crowding agent and their application in purification of oleanic acid.ANALYTICAL METHODS,7(24),10256-10265.
MLA Zhang, C ,et al."Molecularly imprinted polymers prepared using a porogenic solvent of an ionic liquid and a macromolecular crowding agent and their application in purification of oleanic acid".ANALYTICAL METHODS 7.24(2015):10256-10265.
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