Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5)
Mutailipu, M (Mutailipu, Miriding); Hou, DW (Hou, Dianwei); Zhang, M (Zhang, Min); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2016
Source PublicationNEW JOURNAL OF CHEMISTRY
ISSN1144-0546
Volume40Issue:7Pages:6120-6126
Abstract

A series of LiSr1-xPbxBO3 (x = 0.138, 0.285, 0.320, 0.379, 0.417, and 0.5) crystals have been obtained through a high-temperature solution reaction with spontaneous nucleation technique, and the crystal structures were solved from single-crystal X-ray diffraction data. Through a great deal of experiments, it was determined that the maximum value of x cannot be greater than 0.5 possibly because the Sr/Pb-O bond length and the equivalent isotropic displacement parameter of O(3) atoms continuously increased with the increased ratio of Pb2+ cations. It is found that when the Sr atoms were partially substituted with Pb atoms with optical anisotropies, the birefringence improved from 0.0494 at 1064 nm in LiSrBO3 to 0.0721 at 1064 nm in LiSr0.5Pb0.5BO3. Based on the first-principles and real-space atom-cutting method, the origin of birefringence was attributed to the Pb2+ cations and (BO3)(3+) groups in LiSr0.5Pb0.5BO3. The infrared spectrum properties and thermal behavior were also reported.

DOI10.1039/c6nj00390g
Indexed BySCI
WOS IDWOS:000385869600060
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4927
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, M (Zhang, Min)
Affiliation1.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Mutailipu, M ,Hou, DW ,Zhang, M ,et al. Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5)[J]. NEW JOURNAL OF CHEMISTRY,2016,40(7):6120-6126.
APA Mutailipu, M ,Hou, DW ,Zhang, M ,Yang, ZH ,&Pan, SL .(2016).Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5).NEW JOURNAL OF CHEMISTRY,40(7),6120-6126.
MLA Mutailipu, M ,et al."Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5)".NEW JOURNAL OF CHEMISTRY 40.7(2016):6120-6126.
Files in This Item:
File Name/Size DocType Version Access License
Manipulation of bire(1638KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Mutailipu, M (Mutailipu, Miriding)]'s Articles
[Hou, DW (Hou, Dianwei)]'s Articles
[Zhang, M (Zhang, Min)]'s Articles
Baidu academic
Similar articles in Baidu academic
[Mutailipu, M (Mutailipu, Miriding)]'s Articles
[Hou, DW (Hou, Dianwei)]'s Articles
[Zhang, M (Zhang, Min)]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Mutailipu, M (Mutailipu, Miriding)]'s Articles
[Hou, DW (Hou, Dianwei)]'s Articles
[Zhang, M (Zhang, Min)]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 = x = 0.5).pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.