Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5)
Mutailipu, M (Mutailipu, Miriding); Hou, DW (Hou, Dianwei); Zhang, M (Zhang, Min); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2016
发表期刊NEW JOURNAL OF CHEMISTRY
ISSN1144-0546
卷号40期号:7页码:6120-6126
摘要

A series of LiSr1-xPbxBO3 (x = 0.138, 0.285, 0.320, 0.379, 0.417, and 0.5) crystals have been obtained through a high-temperature solution reaction with spontaneous nucleation technique, and the crystal structures were solved from single-crystal X-ray diffraction data. Through a great deal of experiments, it was determined that the maximum value of x cannot be greater than 0.5 possibly because the Sr/Pb-O bond length and the equivalent isotropic displacement parameter of O(3) atoms continuously increased with the increased ratio of Pb2+ cations. It is found that when the Sr atoms were partially substituted with Pb atoms with optical anisotropies, the birefringence improved from 0.0494 at 1064 nm in LiSrBO3 to 0.0721 at 1064 nm in LiSr0.5Pb0.5BO3. Based on the first-principles and real-space atom-cutting method, the origin of birefringence was attributed to the Pb2+ cations and (BO3)(3+) groups in LiSr0.5Pb0.5BO3. The infrared spectrum properties and thermal behavior were also reported.

DOI10.1039/c6nj00390g
收录类别SCI
WOS记录号WOS:000385869600060
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4927
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Zhang, M (Zhang, Min)
作者单位1.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Mutailipu, M ,Hou, DW ,Zhang, M ,et al. Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5)[J]. NEW JOURNAL OF CHEMISTRY,2016,40(7):6120-6126.
APA Mutailipu, M ,Hou, DW ,Zhang, M ,Yang, ZH ,&Pan, SL .(2016).Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5).NEW JOURNAL OF CHEMISTRY,40(7),6120-6126.
MLA Mutailipu, M ,et al."Manipulation of birefringence via substitution of Sr2+ by Pb2+ based on the structure model of LiSr1-xPbxBO3 ( 0 <= x <= 0.5)".NEW JOURNAL OF CHEMISTRY 40.7(2016):6120-6126.
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