Effects of the Orientation of [B5O11](7-) Fundamental Building Blocks on Layered Structures Based on the Pentaborates
Mutailipu, M (Mutailipu, Miriding)1; Zhang, M (Zhang, Min)1; Dong, XY (Dong, Xiaoyu)1; Chen, YN (Chen, Yanna)1; Pan, SL (Pan, Shilie)1
2016
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume55Issue:20Pages:10608-10616
Abstract

Four new layered pentaborates Rb4Ba2.5B20O34Br, Rb2Ba4B20O34Br2, Rb4Ba2.5B20O34Cl, and KBaB5O9 have been successfully synthesized via a high-temperature solution method; the former three are the first series of compounds reported in the Rb-Ba-B-O-X (X = halogen) system. Interestingly, the structures of the above compounds are composed of the same [B5O11](7-) fundamental building block (FBB), which could be further linked to form (2)(infinity)[B10O17](4-) double layers for the former three compounds and (2)(infinity)[B5O9](3-) single layers for the last one. The structure comparisons among all the available anhydrous pentaborates reveal that the structures of the anionic framework are affected by the relationship between the orientation of [B5O11](7-) FBB axes and the layer plane (parallel or perpendicular), which will produce the different number of terminal O atoms in the initial pentaborate blocks. The viewpoints give us a feasible way to investigate the layered structures and expand the structural diversity of borates. Furthermore, the infrared spectra, UV-vis-NIR diffuse reflectance spectra, and thermal behaviors of these compounds were also studied.

DOI10.1021/acs.inorgchem.6b01855
Indexed BySCI
WOS IDWOS:000385785700075
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4926
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, M (Zhang, Min)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Mutailipu, M ,Zhang, M ,Dong, XY ,et al. Effects of the Orientation of [B5O11](7-) Fundamental Building Blocks on Layered Structures Based on the Pentaborates[J]. INORGANIC CHEMISTRY,2016,55(20):10608-10616.
APA Mutailipu, M ,Zhang, M ,Dong, XY ,Chen, YN ,&Pan, SL .(2016).Effects of the Orientation of [B5O11](7-) Fundamental Building Blocks on Layered Structures Based on the Pentaborates.INORGANIC CHEMISTRY,55(20),10608-10616.
MLA Mutailipu, M ,et al."Effects of the Orientation of [B5O11](7-) Fundamental Building Blocks on Layered Structures Based on the Pentaborates".INORGANIC CHEMISTRY 55.20(2016):10608-10616.
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