Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36](9-) Fundamental Building Blocks
Mutailipu, M (Mutailipu, Miriding)1; Zhang, M (Zhang, Min)1; Su, X (Su, Xin)1; Yang, ZH (Yang, Zhihua)1; Pan, SL (Pan, Shilie)1
2017
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume56Issue:10Pages:5506-5509
Abstract

Two noncentrosymmetric borates, Na8MB21O36 (M = Rb and Cs), have been synthesized, structurally analyzed, and characterized for the first time. Their fundamental building block (FBB) is determined as the unprecedented [B21O36](9) units, which is cotemplated by four-connected [BO4](5) and five-connected [B5O11](7) clusters. To the best of our knowledge, the [B21O36](9) FBB has never been reported in borates. Besides, the structure comparisons among all the available anhydrous borates with high-polymeric FBBs were carried out to enlighten the investigation of B-rich borates.

DOI10.1021/acs.inorgchem.7b00671
Indexed BySCI
WOS IDWOS:000401593800005
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4924
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, M (Zhang, Min); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Mutailipu, M ,Zhang, M ,Su, X ,et al. Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36](9-) Fundamental Building Blocks[J]. INORGANIC CHEMISTRY,2017,56(10):5506-5509.
APA Mutailipu, M ,Zhang, M ,Su, X ,Yang, ZH ,&Pan, SL .(2017).Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36](9-) Fundamental Building Blocks.INORGANIC CHEMISTRY,56(10),5506-5509.
MLA Mutailipu, M ,et al."Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36](9-) Fundamental Building Blocks".INORGANIC CHEMISTRY 56.10(2017):5506-5509.
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