Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework
Bai, CY (Bai, Chunyan)1; Yu, HW (Yu, Hongwei)1; Han, SJ (Han, Shujuan)1; Pan, SL (Pan, Shilie)1; Zhang, BB (Zhang, Bingbing)1; Wang, Y (Wang, Ying)1; Wu, HP (Wu, Hongping)1; Yang, ZH (Yang, Zhihua)1
2014
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume53Issue:20Pages:11213-11220
Abstract

The perovskite structure is a good candidate for the design of functional materials. On the basis of the combination of B6O13 groups and XM6 (X = Cl, Br; M = alkali metals) octahedra, three new perovskite-related crystals Na3B6O10Cl, RbNa(2)B6O(10)Cl, and RbNa2B6O10Br have been synthesized by a high-temperature solution method for the first time. Na3B6O10Cl and RbNa2B6O10Cl are isostructural and crystallize in the noncentrosymmetric (NCS) space group P2(1)2(1)2(1) (No. 19), while RbNa2B6O10Br belongs to the centrosymmetric (CS) space group Pnma (No. 62). The phenomenon that Cl-containing borates are not isostructural with corresponding Br-containing borates is extremely rare among borates. Detailed structure analysis suggests that the difference is owing to the effect of the halogen (Cl, Br) on the symmetry of the flexible perovskite-related framework. In addition, thermal analyses, IR spectroscopy, the UV-vis-NIR diffuse reflectance spectrum, and first-principles theoretical studies have also been performed on the three compounds.

DOI10.1021/ic501814q
Indexed BySCI
WOS IDWOS:000343527700053
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4901
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorHan, SJ (Han, Shujuan)
Affiliation1.Xinjiang Tech Inst Phys & Chem CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm CAS, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Bai, CY ,Yu, HW ,Han, SJ ,et al. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework[J]. INORGANIC CHEMISTRY,2014,53(20):11213-11220.
APA Bai, CY .,Yu, HW .,Han, SJ .,Pan, SL .,Zhang, BB .,...&Yang, ZH .(2014).Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework.INORGANIC CHEMISTRY,53(20),11213-11220.
MLA Bai, CY ,et al."Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework".INORGANIC CHEMISTRY 53.20(2014):11213-11220.
Files in This Item:
File Name/Size DocType Version Access License
Effect of Halogen (C(1903KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Bai, CY (Bai, Chunyan)]'s Articles
[Yu, HW (Yu, Hongwei)]'s Articles
[Han, SJ (Han, Shujuan)]'s Articles
Baidu academic
Similar articles in Baidu academic
[Bai, CY (Bai, Chunyan)]'s Articles
[Yu, HW (Yu, Hongwei)]'s Articles
[Han, SJ (Han, Shujuan)]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Bai, CY (Bai, Chunyan)]'s Articles
[Yu, HW (Yu, Hongwei)]'s Articles
[Han, SJ (Han, Shujuan)]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.