Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)
Huang, SS (Huang, Shengshi)1; Jing, Q (Jing, Qun)1; Han, J (Han, Jian)1; Pan, SL (Pan, Shilie)1; Wu, HP (Wu, Hongping)1; Yang, ZH (Yang, Zhihua)1; Han, J
2015
发表期刊EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
期号9页码:1490-1495
摘要Three alkali metal lead orthophosphates, APbPO(4) (A = K, Rb, Cs), have been synthesized by conventional solid-state reaction. The single-crystal X-ray structural analyses revealed that they crystallize in the same space group, Pnma (No. 62), but they are not all isostructural. APbPO(4) (A = K, Rb) are isostructural, and the three-dimensional (3D) structure of RbPbPO4 (representative) consists of [Pb1|Rb1O(4)](infinity) chains connected with isolated PO4 tetrahedra, the Pb2|Rb2 atoms filling the pore space. The 3D structure of CsPbPO4 consists of another kind of chains, [PbO4](infinity), connected with isolated PO4 tetrahedra, and the Cs atoms reside in the channel. Thermal, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy analyses have also been performed. In addition, first-principle theoretical studies were carried out to aid in the understanding of the electronic structures and the projected density of states of CsPbPO4.
关键词Orthophosphates Structure Elucidation Alkali Metals Lead Density Functional Calculations
DOI10.1002/ejic.201403244
收录类别SCI
WOS记录号WOS:000351435100002
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文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4887
专题中国科学院特殊环境功能材料与器件重点试验室
通讯作者Han, J
作者单位1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Huang, SS ,Jing, Q ,Han, J ,et al. Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2015(9):1490-1495.
APA Huang, SS .,Jing, Q .,Han, J .,Pan, SL .,Wu, HP .,...&Han, J.(2015).Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(9),1490-1495.
MLA Huang, SS ,et al."Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .9(2015):1490-1495.
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