Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)
Huang, SS (Huang, Shengshi)1; Jing, Q (Jing, Qun)1; Han, J (Han, Jian)1; Pan, SL (Pan, Shilie)1; Wu, HP (Wu, Hongping)1; Yang, ZH (Yang, Zhihua)1
2015
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue9Pages:1490-1495
Abstract

Three alkali metal lead orthophosphates, APbPO(4) (A = K, Rb, Cs), have been synthesized by conventional solid-state reaction. The single-crystal X-ray structural analyses revealed that they crystallize in the same space group, Pnma (No. 62), but they are not all isostructural. APbPO(4) (A = K, Rb) are isostructural, and the three-dimensional (3D) structure of RbPbPO4 (representative) consists of [Pb1|Rb1O(4)](infinity) chains connected with isolated PO4 tetrahedra, the Pb2|Rb2 atoms filling the pore space. The 3D structure of CsPbPO4 consists of another kind of chains, [PbO4](infinity), connected with isolated PO4 tetrahedra, and the Cs atoms reside in the channel. Thermal, IR spectroscopy, and UV/Vis/NIR diffuse reflectance spectroscopy analyses have also been performed. In addition, first-principle theoretical studies were carried out to aid in the understanding of the electronic structures and the projected density of states of CsPbPO4.

KeywordOrthophosphates Structure Elucidation Alkali Metals Lead Density Functional Calculations
DOI10.1002/ejic.201403244
Indexed BySCI
WOS IDWOS:000351435100002
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Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4887
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorHan, J (Han, Jian)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Huang, SS ,Jing, Q ,Han, J ,et al. Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2015(9):1490-1495.
APA Huang, SS ,Jing, Q ,Han, J ,Pan, SL ,Wu, HP ,&Yang, ZH .(2015).Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(9),1490-1495.
MLA Huang, SS ,et al."Three Alkali Metal Lead Orthophosphates - Syntheses, Crystal Structures and Properties of APbPO(4) (A = K, Rb, Cs)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .9(2015):1490-1495.
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