Ba2B6O11, a Member of the BaO-B2O3 Family, Featuring a Layer Framework
Liu, LL (Liu, Lili); Yang, Y (Yang, Yun); Dong, XY (Dong, Xiaoyu); Lei, C (Lei, Chen); Han, SJ (Han, Shujuan); Pan, SL (Pan, Shilie)
2015
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue20Pages:3328-3335
Abstract

Ba2B6O11, a new member of the BaO-B2O3 family, has been found and features a layered structure. The single-crystal Xray structural analysis revealed that Ba2B6O11 crystallizes in the monoclinic space group P2(1)/c. The parameters of the monoclinic unit cell are a = 9.115(1), b = 7.773(1), c = 12.696(2) angstrom, beta = 100.325(9)degrees, and Z = 4. The new centrosymmetric alkaline earth metal borate, Ba2B6O11, is characterized by a 2D B-O framework composed of the basic building block (B6O14) with the Ba2+ cations filling the channels formed by the (B6O14) units or located between the (B6O10)infinity layers. Ba2B6O11 has a short cut-off edge of 240 nm. Based on a theoretical calculation, it has been proven that Ba2B6O11 has a birefringence of 0.04 and a relatively large indirect band gap of 4.94 eV, which is close to the experimental value of 5.17 eV. Its structure is discussed in terms of the B-O framework and dimensional reduction formalism together with the other structures reported in the BaO-B2O3 phase diagram.

KeywordLayered Compounds Electronic Structure Barium Borates
DOI10.1002/ejic.201500399
Indexed BySCI
WOS IDWOS:000359296600014
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4879
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorYang, Y (Yang, Yun)
Affiliation1.Xinjiang Tech Inst Phys & Chem CAS, Key Lab Funct Mat & Devices Special Environm CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, LL ,Yang, Y ,Dong, XY ,et al. Ba2B6O11, a Member of the BaO-B2O3 Family, Featuring a Layer Framework[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2015(20):3328-3335.
APA Liu, LL ,Yang, Y ,Dong, XY ,Lei, C ,Han, SJ ,&Pan, SL .(2015).Ba2B6O11, a Member of the BaO-B2O3 Family, Featuring a Layer Framework.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(20),3328-3335.
MLA Liu, LL ,et al."Ba2B6O11, a Member of the BaO-B2O3 Family, Featuring a Layer Framework".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .20(2015):3328-3335.
Files in This Item:
File Name/Size DocType Version Access License
Ba2B6O11, a Member o(5575KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, LL (Liu, Lili)]'s Articles
[Yang, Y (Yang, Yun)]'s Articles
[Dong, XY (Dong, Xiaoyu)]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, LL (Liu, Lili)]'s Articles
[Yang, Y (Yang, Yun)]'s Articles
[Dong, XY (Dong, Xiaoyu)]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, LL (Liu, Lili)]'s Articles
[Yang, Y (Yang, Yun)]'s Articles
[Dong, XY (Dong, Xiaoyu)]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: Ba2B6O11, a Member of the BaO-B2O3 Family, Featuring a Layer Framework.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.