K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups
Liu, Q (Liu, Qiong); Zhang, XY (Zhang, Xiangyu); Yang, ZH (Yang, Zhihua); Zhang, FF (Zhang, Fangfang); Liu, LL (Liu, Lili); Han, J (Han, Jian); Li, Z (Li, Zhi); Pan, SL (Pan, Shilie)
2016
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume55Issue:17Pages:8744-8749
Abstract

A potential ultraviolet (UV) nonlinear optical (NLO) material, K3B3O4(OH)(4)center dot 2H(2)O, was successfully synthesized by hydrothermal methods. The compound crystallizes into the Cmc2(1) space group and exhibits isolated [B3O4(OH)(4)](3-) anion groups connected by O-H center dot center dot center dot O hydrogen bonds. The UV vis diffuse reflectance spectrum shows that K3B3O4(OH)(4)center dot 2H(2)O has a wide transparency range with an absorption edge below 190 nm. Powder second harmonic generation (SHG) measurements using 1064 nm radiation revealed a moderate efficiency, 0.8 X KDP. Additional particle size vs SHG efficiency measurements indicate that K3B3O4(OH)(4)center dot 2H(2)O is type I phase-matchable. Our calculated results show that the borate groups as well as the waters of hydration determine the NLO properties of K3B3O4(OH)(4)center dot 2H(2)O.

DOI10.1021/acs.inorgchem.6b01298
Indexed BySCI
WOS IDWOS:000382713900058
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4855
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorYang, ZH (Yang, Zhihua); Li, Z (Li, Zhi); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, Q ,Zhang, XY ,Yang, ZH ,et al. K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups[J]. INORGANIC CHEMISTRY,2016,55(17):8744-8749.
APA Liu, Q .,Zhang, XY .,Yang, ZH .,Zhang, FF .,Liu, LL .,...&Pan, SL .(2016).K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups.INORGANIC CHEMISTRY,55(17),8744-8749.
MLA Liu, Q ,et al."K3B3O4(OH)(4)center dot 2H(2)O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)(4)](3-) Anion Groups".INORGANIC CHEMISTRY 55.17(2016):8744-8749.
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