The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density
Liu, LL (Liu, Lili); Yang, Y (Yang, Yun); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2017
Source PublicationJOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
Volume717Issue:9Pages:317-325
Abstract

Single crystals of a new series of alkaline metal molybdates, LiNa3(MoO4)(2) and LiAMo(3)O(10) (A - K+, Rb+, Cs+), have been successfully synthesized through conventional high-temperature solid-state reactions. The compounds are structurally characterized by single-crystal X-ray diffraction and exhibit three-dimensional (3D) crystal structures consisting of 0D or 1D Mo-O framework. Interestingly, when Mo-O dimensionality changes from 0D of LiNa3(MoO4)(2) to 1D of LiAMo(3)O(10), the birefringence of LiAMo(3)O(10) is significantly enhanced to as large as BaTeMo2O9 and Na2TeW2O9. The differences of bandgaps induced by anionic-group dimensionality are also discussed based on structural and theoretical analyses, which illuminate that the bandgap tends to be relatively broad for compounds with isolated MoO4 tetrahedra in alkaline metal molybdate family. In addition, the dimensional reduction formalism was applied in the alkaline metal molybdate system to explore the changes of Mo-O framework along with cation/Mo ratio for the first time.

KeywordAlkaline Metal Molybdates Crystal Structures Enhancement Of Birefringence Bandgap Theoretical Calculations
DOI10.1016/j.jallcom.2017.05.065
Indexed BySCI
WOS IDWOS:000402931200041
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4828
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorPan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, LL ,Yang, Y ,Yang, ZH ,et al. The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2017,717(9):317-325.
APA Liu, LL ,Yang, Y ,Yang, ZH ,&Pan, SL .(2017).The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density.JOURNAL OF ALLOYS AND COMPOUNDS,717(9),317-325.
MLA Liu, LL ,et al."The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density".JOURNAL OF ALLOYS AND COMPOUNDS 717.9(2017):317-325.
Files in This Item:
File Name/Size DocType Version Access License
The enhancement of b(2026KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, LL (Liu, Lili)]'s Articles
[Yang, Y (Yang, Yun)]'s Articles
[Yang, ZH (Yang, Zhihua)]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, LL (Liu, Lili)]'s Articles
[Yang, Y (Yang, Yun)]'s Articles
[Yang, ZH (Yang, Zhihua)]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, LL (Liu, Lili)]'s Articles
[Yang, Y (Yang, Yun)]'s Articles
[Yang, ZH (Yang, Zhihua)]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.