Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units
Mutailipu, M (Mutailipu, Miriding); Su, X (Su, Xin); Zhang, M (Zhang, Min); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
2017
Source PublicationInorganic Chemistry Frontiers
ISSN2052-1553
Volume4Issue:2Pages:281-288
Abstract

Two new members of zincoborate fluoride series Ban+2Znn(BO3)(n)(B2O5)F-n (n = 1, 2), namely, Ba3Zn(BO3)(B2O5)F and Ba4Zn2(BO3)(2)(B2O5)F-2 were firstly synthesized as high-quality single crystals via a high-temperature solution method by adjusting the molar ratios of reactants. They were structurally determined by single-crystal X-ray diffraction and their structures can be regarded as three dimensional (3D) framework stacking of (2)(infinity)[Zn2B6O16](10-) layers for Ba3Zn(BO3)(B2O5)F and (2)(infinity)[Zn2B4O8O5/2O1/3](17/3-) layers for Ba4Zn2(BO3)(2)(B2O5) F-2. To the best of our knowledge, the two title compounds are the first examples of two kinds of isolated B-O groups that coexist in one zincoborate halide. The structure comparisons were carried out among all the available anhydrous-zincoborates, and it is interesting to conclude that about 80% of zincoborates contain isolated B-O clusters and notably the molar ratio of cation/boron (A/B) affects the polymerization of isolated B-O configuration. What's more, the first-principles calculations, infrared spectra, and UV-vis-NIR diffuse reflectance spectra of title compounds have also been performed.

DOI10.1039/c6qi00467a
Indexed BySCI
WOS IDWOS:000395802300007
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/4798
Collection中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
Corresponding AuthorZhang, M (Zhang, Min); Pan, SL (Pan, Shilie)
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Mutailipu, M ,Su, X ,Zhang, M ,et al. Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units[J]. Inorganic Chemistry Frontiers,2017,4(2):281-288.
APA Mutailipu, M ,Su, X ,Zhang, M ,Yang, ZH ,&Pan, SL .(2017).Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units.Inorganic Chemistry Frontiers,4(2),281-288.
MLA Mutailipu, M ,et al."Ban+2Znn(BO3)(n)(B2O5)F-n (n=1, 2): new members of the zincoborate fluoride series with two kinds of isolated B-O units".Inorganic Chemistry Frontiers 4.2(2017):281-288.
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