Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth
Zhang, BB (Zhang, Bingbing); Shi, GQ (Shi, Guoqiang); Yang, ZH (Yang, Zhihua); Zhang, FF (Zhang, Fangfang); Pan, SL (Pan, Shilie); Yang, ZH; Pan, SL
2017
发表期刊ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
卷号56期号:14页码:3916-3919
摘要

Deep-ultraviolet nonlinear optical (DUV NLO) crystals are the key materials to extend the output range of solid-state lasers to below 200 nm. The only practical material KBe2BO3F2 suffers high toxicity through beryllium and strong layered growth. Herein, we propose a beryllium-free material design and synthesis strategy for DUV NLO materials. Introducing the (BO3F)(4-),(BO2F2)(3-), and (BOF3)(2-) groups in borates could break through the fixed 3DB-O network that would produce a larger birefringence without layering and simultaneously keep a short cutoff edge down to DUV. The theoretical and experimental studies on a series of fluorooxoborates confirm this strategy. Li2B6O9F2 is identified as aDUV NLO material with a large second harmonic generation efficiency (0.9 x KDP) and a large predicted birefringence (0.07) without layering. This study provides a feasible way to break down the DUV wall for NLO materials.

关键词Boron Deep-ultraviolet Fluorooxoborates Nonlinear Optical Materials Second Harmonic Generation
DOI10.1002/anie.201700540
收录类别SCI
WOS记录号WOS:000397346200024
引用统计
被引频次:100[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/4776
专题中国科学院特殊环境功能材料与器件重点试验室
材料物理与化学研究室
通讯作者Yang, ZH; Pan, SL
作者单位1.Chinese Acad Sci, Dev Special Environm, Key Lab Funct Mat, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Dev, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Zhang, BB ,Shi, GQ ,Yang, ZH ,et al. Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(14):3916-3919.
APA Zhang, BB .,Shi, GQ .,Yang, ZH .,Zhang, FF .,Pan, SL .,...&Pan, SL.(2017).Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(14),3916-3919.
MLA Zhang, BB ,et al."Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.14(2017):3916-3919.
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